百科

(2R,4aR,6S,7R,8R,8aR)-8-(allyloxy)-6-(((2R,4aR,6S,7R,8R,8aR)-7-hydroxy-2-phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxin-8-yl)oxy)-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7R,8R,8aR)-8-(allyloxy)-6-(((2R,4aR,6S,7R,8R,8aR)-7-hydroxy-2-phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxin-8-yl)oxy)-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-7-ol

CAS号：287945-03-3

英文名：(2R,4aR,6S,7R,8R,8aR)-8-(allyloxy)-6-(((2R,4aR,6S,7R,8R,8aR)-7-hydroxy-2-phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxin-8-yl)oxy)-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-7-ol

分子式：C35H38O10S

分子量：650.735

合成路线

(2R,4aR,6S,6aR,9aR,10S,10aR,12R,14aR,15aS,16aS,16bR)-10-(allyloxy)-2,8,12-triphenyl-6-(phenylthio)dodecahydro-[1,3]dioxino[4',5':5,6]pyrano[3,2-d][1,3]dioxino[4',5':5,6]pyrano[4,3-g][1,3,6]trioxocine

(2R,4aR,6S,6aR,9aR,10S,10aR,12R,14aR,15aS,16aS,16bR)-10-(allyloxy)-2,8,12-triphenyl-6-(phenylthio)dodecahydro-[1,3]dioxino[4',5':5,6]pyrano[3,2-d][1,3]dioxino[4',5':5,6]pyrano[4,3-g][1,3,6]trioxocine

(2R,4aR,6S,7R,8R,8aR)-8-(allyloxy)-6-(((2R,4aR,6S,7R,8R,8aR)-7-hydroxy-2-phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxin-8-yl)oxy)-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7R,8R,8aR)-8-(allyloxy)-6-(((2R,4aR,6S,7R,8R,8aR)-7-hydroxy-2-phenyl-6-(phenylthio)hexahydropyrano[3,2-d][1,3]dioxin-8-yl)oxy)-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-7-ol

上游原料

(2R,4aR,6S,6aR,9aR,10S,10aR,12R,14aR,15aS,16aS,16bR)-10-(allyloxy)-2,8,12-triphenyl-6-(phenylthio)dodecahydro-[1,3]dioxino[4',5':5,6]pyrano[3,2-d][1,3]dioxino[4',5':5,6]pyrano[4,3-g][1,3,6]trioxocine

下游产品

11-{3-[4-(4-allyloxy-5-benzyloxy-3-hydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-5-benzyloxy-3-hydroxy-6-methyl-tetrahydro-pyran-2-yloxy]-4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy}-tetradecanoic acid (2S,3R,4R,5R,6R)-4-(allyloxy)-5-(benzyloxy)-2-(((2R,3R,4R,5R,6S)-3-(benzyloxy)-5-hydroxy-2-(hydroxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-4-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3-ol phenyl 3'-O-allyl-2,2'-di-O-benzoyl-4,4'-di-O-benzyl-6,6'-dideoxy-1-thio-β-D-laminaribioside