百科

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

CAS号：287945-07-7

英文名：(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

分子式：C36H54O10S

分子量：678.873

合成路线

Benzoic acid (S)-11-benzyloxy-1-propyl-undecyl ester

Benzoic acid (S)-11-benzyloxy-1-propyl-undecyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

phenyl 2-O-acetyl-3,4-di-O-benzyl-6-O-mesyl-1-thio-β-D-glucopyranoside

phenyl 2-O-acetyl-3,4-di-O-benzyl-6-O-mesyl-1-thio-β-D-glucopyranoside

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

Benzoic acid (R)-11-benzyloxy-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-undecyl ester

Benzoic acid (R)-11-benzyloxy-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-undecyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(2S)-2,5-dihydroxy-1-tosyloxypentane

(2S)-2,5-dihydroxy-1-tosyloxypentane

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(2S)-toluene-4-sulfonic acid 5-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-pentyl ester

(2S)-toluene-4-sulfonic acid 5-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-pentyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(S)-tetradecan-1,11-diol

(S)-tetradecan-1,11-diol

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

(S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methanesulfonyloxymethyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester

上游原料

phenyl 2-O-acetyl-3,4-di-O-benzyl-6-O-mesyl-1-thio-β-D-glucopyranoside Benzoic acid (R)-11-benzyloxy-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-undecyl ester Benzoic acid (S)-11-benzyloxy-1-propyl-undecyl ester (2S)-2,5-dihydroxy-1-tosyloxypentane (S)-tetradecan-1,11-diol (2S)-toluene-4-sulfonic acid 5-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-pentyl ester

下游产品

11-{3-[4-(4-allyloxy-5-benzyloxy-3-hydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-5-benzyloxy-3-hydroxy-6-methyl-tetrahydro-pyran-2-yloxy]-4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy}-tetradecanoic acid (S)-11-((2R,3R,4R,5R,6R)-4,5-Bis-benzyloxy-3-hydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetradecanoic acid methyl ester