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methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

CAS号：288374-80-1

英文名：methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

分子式：C29H40O7SSi

分子量：560.774

合成路线

(3R,4S,6R)-3-hydroxy-4-methyl-5-oxo-6-[(tert-butyl-dimethylsilyl)oxy]-6-phenylhexanal

(3R,4S,6R)-3-hydroxy-4-methyl-5-oxo-6-[(tert-butyl-dimethylsilyl)oxy]-6-phenylhexanal

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

(R)-(-)-N-methyl-N-methoxy(2-hydroxy-2-phenyl)acetamide

(R)-(-)-N-methyl-N-methoxy(2-hydroxy-2-phenyl)acetamide

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

(R)-(+)-(1-tert-butyldimethylsilyloxy-1-phenyl)butan-2-one

(R)-(+)-(1-tert-butyldimethylsilyloxy-1-phenyl)butan-2-one

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

(R)-(-)-N-methyl-N-methoxy(2-tert-butyldimethylsilyloxy-2-phenyl)acetamide

(R)-(-)-N-methyl-N-methoxy(2-tert-butyldimethylsilyloxy-2-phenyl)acetamide

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

(3R,4S,6R)-1,1-diethoxy-3-hydroxy-4-methyl-5-oxo-6-[(tert-butyl-dimethylsilyl)oxy]-6-phenylhexane

(3R,4S,6R)-1,1-diethoxy-3-hydroxy-4-methyl-5-oxo-6-[(tert-butyl-dimethylsilyl)oxy]-6-phenylhexane

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

methyl (5R,6S,8R)-5-tosyloxy-6-methyl-7-oxo-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate

上游原料

(R)-(+)-(1-tert-butyldimethylsilyloxy-1-phenyl)butan-2-one (R)-(-)-N-methyl-N-methoxy(2-tert-butyldimethylsilyloxy-2-phenyl)acetamide (R)-(-)-N-methyl-N-methoxy(2-hydroxy-2-phenyl)acetamide (3R,4S,6R)-3-hydroxy-4-methyl-5-oxo-6-[(tert-butyl-dimethylsilyl)oxy]-6-phenylhexanal (3R,4S,6R)-1,1-diethoxy-3-hydroxy-4-methyl-5-oxo-6-[(tert-butyl-dimethylsilyl)oxy]-6-phenylhexane

下游产品

methyl (5R,6R,7R,8R)-5-tosyloxy-6-methyl-7-hydroxy-8-[(tert-butyl-dimethylsilyl)oxy]-8-phenyl-oct-2(E)-enoate