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2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

CAS号：292864-88-1

英文名：2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

分子式：C30H31NO4Si

分子量：497.657

合成路线

methyl 3-deoxy-3-methylene-D-erythro-pentofuranoside

methyl 3-deoxy-3-methylene-D-erythro-pentofuranoside

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

(3R,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahdyro-4-methylidenefuran-3-ol

(3R,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahdyro-4-methylidenefuran-3-ol

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

3-deoxy-1,2-O-isopropylidene-3-methylidene-5-O-trityl-α-D-ribofuranose

3-deoxy-1,2-O-isopropylidene-3-methylidene-5-O-trityl-α-D-ribofuranose

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

1,2-O-isopropylidene-5-O-(triphenylmethyl)-α-D-erythro-pentofuranos-3-ulose

1,2-O-isopropylidene-5-O-(triphenylmethyl)-α-D-erythro-pentofuranos-3-ulose

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

(2S,4R)-tetrahdyro-4-hydroxy-3-methylidenefuran-2-methanol

(2S,4R)-tetrahdyro-4-hydroxy-3-methylidenefuran-2-methanol

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

2-{(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-yl}-1H-isoindol-1,3(2H)-dione

上游原料

1,2-O-isopropylidene-5-O-(triphenylmethyl)-α-D-erythro-pentofuranos-3-ulose 3-deoxy-1,2-O-isopropylidene-3-methylidene-5-O-trityl-α-D-ribofuranose (3R,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahdyro-4-methylidenefuran-3-ol methyl 3-deoxy-3-methylene-D-erythro-pentofuranoside (2S,4R)-tetrahdyro-4-hydroxy-3-methylidenefuran-2-methanol

下游产品

(3S,5S)-5-{{[(tert-butyl)diphenylsilyl]oxy}methyl}tetrahydro-4-methylidenefuran-3-amine