(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

CAS号：293751-13-0

英文名：(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

分子式：C25H23N5O5

分子量：473.481

合成路线

(1S,3R,4R,7S)-7-benzyloxy-3-(hypoxanthin-9-yl)-1-methanesulfonyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

(1S,3R,4R,7S)-7-benzyloxy-3-(hypoxanthin-9-yl)-1-methanesulfonyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-1-benzoyloxymethyl-7-benzyloxy-3-(6-chloropurin-9-yl)-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-1-benzoyloxymethyl-7-benzyloxy-3-(6-chloropurin-9-yl)-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

(1S,3R,4R,7S)-1-benzoyloxymethyl-7-benzyloxy-3-(hypoxanthin-9-yl)-2,5-dioxabicyclo[2.2.1]heptane

(1S,3R,4R,7S)-1-benzoyloxymethyl-7-benzyloxy-3-(hypoxanthin-9-yl)-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

1-(2-O-acetyl-3-O-benzyl-4-C-methanesulfonoxymethyl-5-O-methanesulfonyl-β-D-erythro-pentofuranosyl)-6-N-benzoyladenine

1-(2-O-acetyl-3-O-benzyl-4-C-methanesulfonoxymethyl-5-O-methanesulfonyl-β-D-erythro-pentofuranosyl)-6-N-benzoyladenine

(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

(1R,3R,4R,7S)-3-(adenine-9-yl)-7-benzyloxy-1-benzoyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane

上游原料

1-(2-O-acetyl-3-O-benzyl-4-C-methanesulfonoxymethyl-5-O-methanesulfonyl-β-D-erythro-pentofuranosyl)-6-N-benzoyladenine (1S,3R,4R,7S)-7-benzyloxy-3-(hypoxanthin-9-yl)-1-methanesulfonyloxymethyl-2,5-dioxabicyclo[2.2.1]heptane (1R,3R,4R,7S)-1-benzoyloxymethyl-7-benzyloxy-3-(6-chloropurin-9-yl)-2,5-dioxabicyclo[2.2.1]heptane (1S,3R,4R,7S)-1-benzoyloxymethyl-7-benzyloxy-3-(hypoxanthin-9-yl)-2,5-dioxabicyclo[2.2.1]heptane

下游产品

(1S,3R,4R,7S)-3-(6-amino-9H-purin-9-yl)-1-(hydroxymethyl)-2,5-dioxabicyclo[2.2.1]heptan-7-ol (1S,3R,4R,7S)-3-(6-N-benzoyladenine-9-yl)-7-hydroxy-1-hydroxymethyl-2,5-dioxabicyclo[2.2.1]heptane