合成路线
![(2R,3S,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-hex-5-ene-1,2-diol](https://cdn-oss.0elem.com/prod/mob/images/299/299411-06-6.jpg)
(2R,3S,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-hex-5-ene-1,2-diol
CAS号：299411-06-6
英文名：(2R,3S,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-hex-5-ene-1,2-diol
分子式：C22H48O5Si2
分子量：448.785
![(2S,3S,4S,5S,6S)-6-Bromomethyl-5-(tert-butyl-dimethyl-silanyloxy)-4-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-2-methoxy-tetrahydro-pyran-3-ol](https://cdn-oss.0elem.com/prod/mob/images/299/299411-04-4.jpg)
![methyl 4-O-benzoyl-6-bromo-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-6-deoxy-α-D-altropyranoside](https://cdn-oss.0elem.com/prod/mob/images/299/299410-98-3.jpg)
![(2R,4aR,6S,7S,8S,8aR)-8-(4-Hydroxy-butoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol](https://cdn-oss.0elem.com/prod/mob/images/299/299410-94-9.jpg)
![(2S,3S,4R,5S,6S)-2-Bromomethyl-4-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-6-methoxy-tetrahydro-pyran-3,5-diol](https://cdn-oss.0elem.com/prod/mob/images/299/299411-00-0.jpg)
![methyl 4,6-O-benzylidene-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-α-D-altropyranoside](https://cdn-oss.0elem.com/prod/mob/images/299/299410-96-1.jpg)
![(2S,3S,4R,5S,6S)-2-Bromomethyl-3,5-bis-(tert-butyl-dimethyl-silanyloxy)-4-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-6-methoxy-tetrahydro-pyran](https://cdn-oss.0elem.com/prod/mob/images/299/299411-02-2.jpg)
上游原料
(2S,3S,4R,5S,6S)-2-Bromomethyl-4-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-6-methoxy-tetrahydro-pyran-3,5-diol
methyl 4,6-O-benzylidene-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-α-D-altropyranoside
(2S,3S,4S,5S,6S)-6-Bromomethyl-5-(tert-butyl-dimethyl-silanyloxy)-4-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-2-methoxy-tetrahydro-pyran-3-ol
methyl 4-O-benzoyl-6-bromo-3-O-[4-{(tert-butyldimethylsilyl)oxy}butyl]-6-deoxy-α-D-altropyranoside
(2S,3S,4R,5S,6S)-2-Bromomethyl-3,5-bis-(tert-butyl-dimethyl-silanyloxy)-4-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-6-methoxy-tetrahydro-pyran
methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside
(2R,4aR,6S,7S,8S,8aR)-8-(4-Hydroxy-butoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol
下游产品
(R)-2-{(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-but-3-enyl}-oxirane
(3R,4S,5R)-3,5-bis(tert-butyldimethylsilyloxy)-4-[4-(tert-butyldimethylsilyloxy)butoxy]oct-1-en-7-yne
(4R,5S,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-oct-7-en-1-yn-4-ol
(R)-6-{(1R,3aS,7aR)-4-[2-[(3R,4S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-4-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-2-methylene-cyclohex-(Z)-ylidene]-eth-(E)-ylidene]-7a-methyl-octahydro-inden-1-yl}-2-methyl-heptan-2-ol
(4R,5S,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-[4-(tert-butyl-dimethyl-silanyloxy)-butoxy]-1-trimethylsilanyl-oct-7-en-1-yn-4-ol
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