百科

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

CAS号：299411-13-5

英文名：(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

分子式：C23H46O4Si2

分子量：442.78

合成路线

methyl 6-bromo-2,4-bis-(O-tert-butyldimethylsilyl)-3-O-[3-{(tert-butyldimethylsilyl)oxy}propyl]-6-deoxy-α-D-altropyranoside

methyl 6-bromo-2,4-bis-(O-tert-butyldimethylsilyl)-3-O-[3-{(tert-butyldimethylsilyl)oxy}propyl]-6-deoxy-α-D-altropyranoside

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

methyl 6-bromo-3-O-[3-{(tert-butyldimethylsilyl)oxy}propyl]-6-deoxy-α-D-altropyranoside

methyl 6-bromo-3-O-[3-{(tert-butyldimethylsilyl)oxy}propyl]-6-deoxy-α-D-altropyranoside

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

(2R,3S,4R)-4-[(t-butyldimethylsilyl)oxy]-3-[3-{(t-butyldimethylsilyl)oxy}propoxy]hex-5-ene-1,2-diol

(2R,3S,4R)-4-[(t-butyldimethylsilyl)oxy]-3-[3-{(t-butyldimethylsilyl)oxy}propoxy]hex-5-ene-1,2-diol

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

(R)-2-{(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[3-(tert-butyl-dimethyl-silanyloxy)-propoxy]-but-3-enyl}-oxirane

(R)-2-{(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[3-(tert-butyl-dimethyl-silanyloxy)-propoxy]-but-3-enyl}-oxirane

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

methyl 6-bromo-4-(O-tert-butyldimethylsilyl)-3-O-[3-{(tert-butyldimethylsilyl)oxy}propyl]-6-deoxy-α-D-altropyranoside

methyl 6-bromo-4-(O-tert-butyldimethylsilyl)-3-O-[3-{(tert-butyldimethylsilyl)oxy}propyl]-6-deoxy-α-D-altropyranoside

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

(4R,5S,6R)-6-[(t-butyldimethylsilyl)oxy]-5-[3-{(t-butyldimethylsilyl)oxy}propoxy]oct-7-en-1-yn-4-ol

上游原料

(2R,3S,4R)-4-[(t-butyldimethylsilyl)oxy]-3-[3-{(t-butyldimethylsilyl)oxy}propoxy]hex-5-ene-1,2-diol methyl 6-bromo-4-(O-tert-butyldimethylsilyl)-3-O-[3-{(tert-butyldimethylsilyl)oxy}propyl]-6-deoxy-α-D-altropyranoside methyl 6-bromo-2,4-bis-(O-tert-butyldimethylsilyl)-3-O-[3-{(tert-butyldimethylsilyl)oxy}propyl]-6-deoxy-α-D-altropyranoside methyl 4,6-O-benzylidene-2,3-anhydro-β-mannopyranoside methyl 6-bromo-3-O-[3-{(tert-butyldimethylsilyl)oxy}propyl]-6-deoxy-α-D-altropyranoside (R)-2-{(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-[3-(tert-butyl-dimethyl-silanyloxy)-propoxy]-but-3-enyl}-oxirane

下游产品

(R)-6-{(1R,3aS,7aR)-4-[2-[(3R,4S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-4-[3-(tert-butyl-dimethyl-silanyloxy)-propoxy]-2-methylene-cyclohex-(Z)-ylidene]-eth-(E)-ylidene]-7a-methyl-octahydro-inden-1-yl}-2-methyl-heptan-2-ol