百科

(2R,4RS,6R)-1-tert-butyldimethylsilyloxy-2,6-dimethyl-4-phenylsulfonyl-7-tetrahydropyranyloxyheptane

(2R,4RS,6R)-1-tert-butyldimethylsilyloxy-2,6-dimethyl-4-phenylsulfonyl-7-tetrahydropyranyloxyheptane

CAS号：299430-21-0

英文名：(2R,4RS,6R)-1-tert-butyldimethylsilyloxy-2,6-dimethyl-4-phenylsulfonyl-7-tetrahydropyranyloxyheptane

分子式：C26H46O5SSi

分子量：498.791

合成路线

(2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane

(2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane

(R)-2-methyl-4-phenylsulfonyl-1-tetrahydropyranyloxybutane

(R)-2-methyl-4-phenylsulfonyl-1-tetrahydropyranyloxybutane

(2R,4RS,6R)-1-tert-butyldimethylsilyloxy-2,6-dimethyl-4-phenylsulfonyl-7-tetrahydropyranyloxyheptane

(2R,4RS,6R)-1-tert-butyldimethylsilyloxy-2,6-dimethyl-4-phenylsulfonyl-7-tetrahydropyranyloxyheptane

(R)-3-Methyl-4-<(tetrahydropyranyl)oxy>-1-iodobutane

(R)-3-Methyl-4-<(tetrahydropyranyl)oxy>-1-iodobutane

(2R,4RS,6R)-1-tert-butyldimethylsilyloxy-2,6-dimethyl-4-phenylsulfonyl-7-tetrahydropyranyloxyheptane

(2R,4RS,6R)-1-tert-butyldimethylsilyloxy-2,6-dimethyl-4-phenylsulfonyl-7-tetrahydropyranyloxyheptane

上游原料

(2S)-(+)-(tert-butyl-dimethyl)-(3-iodo-2-methyl-propoxy)-silane (R)-3-Methyl-4-<(tetrahydropyranyl)oxy>-1-iodobutane (R)-2-methyl-4-phenylsulfonyl-1-tetrahydropyranyloxybutane

下游产品

(2R,6S)-2,6-dimethyl-1-tetrahydropyranyloxypentadecane (2S,6R)-2,6-dimethyl-1-pentadecanol (2R,6R)-2,6-dimethyl-7-tetrahydropyranyloxy-1-heptanol (2R,6R)-1-tert-butyldimethylsilyloxy-2,6-dimethyl-7-tetrahydropyranyloxyheptane (2R,6S)-2,6-dimethyl-1-decyl tosylate (2R,6S)-2,6-dimethyl-1-tetradecanol (2R,6S)-2,6-dimethyl-1-tetrahydropyranyloxytetradecane (2R,6S)-2,6-dimethylpentadecyl tosylate (2R,6S)-2,6-dimethyl-1-decanol (2R,6S)-2,6-dimethyl-1-pentadecanol (2S,6R)-2,6-dimethylpentadecyl tosylate (2R,6S)-2,6-dimethyl-1-tetrahydropyranyloxydecane (2R,6R)-2,6-dimethyl-7-tetrahydropyranyloxyheptyl p-toleuenesulfonate (5S,9S)-5,9-Dimethyloctadecane (2R,6S)-2,6-dimethyltetradecyl tosylate (10S,14S)-10,14-dimethyl-1-octadecene