合成路线
查看更多
巨大戟萜醇
CAS号：30220-46-3
英文名：ingenol
分子式：C20H28O5
分子量：348.433
上游原料
tert-butyl(((1R,2R)-1-((1R,2R,3R,4R,6R)-3-ethynyl-4,7,7-trimethyl-3-((trimethylsilyl)oxy)bicyclo[4.1.0]heptan-2-yl)-2-methylpenta-3,4-dien-1-yl)oxy)dimethylsilane
(1aR,1bR,2R,3R,7bR,8R,9aR)-2-((tert-butyldimethylsilyl)oxy)-1,1,3,8-tetramethyl-7b-((trimethylsilyl)oxy)-1,1a,1b,2,3,5,7b,8,9,9a-decahydro-6H-cyclopropa[3,4]benzo[1,2-e]azulen-6-one
(1aR,1bR,2R,3R,4R,4aS,6S,7bR,8R,9aR)-2-((tert-butyldimethylsilyl)oxy)-1,1,3,6,8-penta-methyl-7b-((trimethylsilyl)oxy)-1,1a,1b,2,3,4,5,6,7b,8,9,9a-dodecahydro-4aH-cyclopropa[3,4]benzo[1,2-e]azulene-4,4a,6-triol
(2S,3aS,6aR,7R,8R,8bR,9aR,11R,11aR)-8-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2,7,9,9,11-pentamethyl-11a-((trimethylsilyl)oxy)-2,3,6a,7,8,8a,8b,9,9a,10,11,11a-dodecahydro-cyclopropa[5',6']benzo[1',2':7,8]azuleno[3a,4-d][1,3]dioxol-5-one
(1R,2R,4R,6R)-2-((1R,2R)-1-hydroxy-2-methyl-penta-3,4-dien-1-yl)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-one
(3S,3aS,6aR,7R,8R,9R,9aR,10aR,12R,12aS)-8-((tert-butyldimethylsilyl)oxy)-2,7,10,10,12-pentamethyl-5,13-dioxo-6a,7,9,9a,10,10a,11,12-octahydro-3H,8H-9,12a-methanocyclopenta[1,10]cyclopropa[6,7]cyclodeca[1,2-d][1,3]dioxol-3-yl acetate
(1R,2R,3R,4R,6R)-3-ethynyl-2-((1R,2R)-1-hydroxy-2-methyl-penta-3,4-dien-1-yl)-4,7,7-trimethylbicyclo[4.1.0]heptan-3-ol
(2aS,5aR,5bR,6aS,8S,8aR,9aR,11R,11aS)-6a-(hydroxymethyl)-2,4,4,9,9,11-hexamethyl-5b,6a,8,8a,9,9a,10,11-octahydro-2aH,7H-8,11a-methanocyclopropa[5',6']oxireno[2'',3'':9',10']cyclodeca[1',2':1,5]cyclopenta[1,2-d][1,3]dioxol-12-one
(3S,3aS,6aR,7S,8R,9R,9aR,10aR,12R,12aS)-8-hydroxy-2,7,10,10,12pentamethyl-5,13-dioxo-6a,7,9,9a,10,10a,11,12-octahydro-3H,8H-9,12a-methanocyclopenta[1,10]cyclopropa[6,7]cyclodeca[1,2-d][1,3 ]dioxol-3-yl acetate
((2aS,5aR,5bR,6aS,8S,8aR,9aR,11R,11aS)-2,4,4,9,9,11-hexamethyl-12-oxo-8,8a,9,9a,10,11-hexahydro-2aH,7H-8,11a-methanocyclopropa[5',6']oxireno[2'',3'':9',10']cyclodeca[1',2':1,5]cyclopenta[1,2-d][1,3]dioxol-6a(5bH)-yl)methyl methanesulfonate
(R)-2-methylpenta-3,4-dien-1-al
(2aS,5aS,6R,9S,9aR,10aR,12R,12aS)-6-hydroxy-2,4,4,10,10,12-hexamethyl-7-((phenylsulfonyl)methyl)-9,9a,10,10a,11,12-hexahydro-2aH,6H-9,12a-methanocyclopropa[5',6']cyclodeca[1',2':1,5]cyclopenta[1,2-d][1,3]dioxol-13-one
(1S,3R,6R)-4-chloro-7,7-dimethylbicyclo[4.1.0]heptan-3-one
(1aR,2S,5aS,8aR,9R,10aR)-4-(((4-methoxybenzyl)oxy)methyl)-1,1,9-trimethyl-7-methylene-1,1a,2,3,5a,7,8,9,10,10a-decahydro-6H-2,8a-methanocyclopenta[a]cyclopropa[e][10]annulene-6,11-dione
(1aR,2S,5aS,8aR,9R,10aR)-7-(hydroxymethyl)-4-(((4-methoxybenzyl)oxy)methyl)-1,1,9-trimethyl-1a,2,3,5a,6,7,8,9,10,10a-decahydro-1H-2,8a-methanocyclopenta[a]cyclopropa[e][10]annulen-11-one
(2aS,5aR,5bS,6aR,8S,8aR,9aR,11R,11aS)-2,4,4,9,9,11-hexamethyl-6a-((phenylthio)methyl)-5b,6a,8,8a,9,9a,10,11-octahydro-2aH,7H-8,11a-methanocyclopropa[5',6']oxireno[2'',3'':9',10']cyclodeca[1',2':1,5]cyclopenta[1,2-d][1,3]dioxol-12-one
(3aS,6aR,7R,8R,9R,9aR,10aR,12R,12aS)-8-((tert-butyldimethylsilyl)oxy)-2,7,10,10,12-pentamethyl-6a,7,9,9a,10,10a,12,12-octahydro-3H,8H-9,12a-methanocyclopenta[1,10]cyclopropa[6,7]cyclodeca[1,2-d][1,3]dioxole-5,13-dione
(1aR,2S,5aS,7S,8aR,9R,10aR)-7-(1,3-dioxolan-2-yl)-4-(((4-methoxybenzyl)oxy)methyl)-1,1,9-trimethyl-1a,2,3,5a,6,7,8,9,10,10a-decahydro-1H-2,8a-methanocyclopenta[a]cyclopropa[e][10]annulen-11-one
二乙酰基苯甲酰基香豌豆醇
cis-carane-4-one
(2aS,5aR,5bS,6aR,8S,8aR,9aR,11R,11aS)-2,4,4,9,9,11-hexamethyl-6a-((phenylsulfonyl)methyl)-5b,6a,8,8a,9,9a,10,11-octahydro-2aH,7H-8,11a-methanocyclopropa[5',6']oxireno[2'',3'':9',10']cyclodeca[1',2':1,5]cyclopenta[1,2-d][1,3]dioxol-12-one
(R)-2-methylpenta-3,4-dien-1-ol
(+)-3-蒈烯
(1aR,2S,5aS,8aR,9R,10aR)-4-(((4-methoxybenzyl)oxy)methyl)-1,1,9-trimethyl-7-methylene-1a,2,3,5a,6,7,8,9,10,10a-decahydro-1H-2,8a-methanocyclopenta[a]cyclopropa[e][10]annulen-11-one
巨大戟醇-5,20-缩丙酮
(1aR,1bR,2R,3R,6S,7bR,8R,9aR)-2-((tert-butyldimethylsilyl)oxy)-1,1,3,6,8-pentamethyl-7b-((trimethylsilyl)oxy)-1a,1b,2,3,5,6,7b,8,9,9a-decahydro-1H-cyclopropa[3,4]benzo[1,2-e]azulen-6-ol
3,4-O-isopropylidene-20-deoxyingenol
(1aR,2S,5aS,6R,8aR,9R,10aR)-6-hydroxy-4-(((4-methoxybenzyl)oxy)methyl)-1,1,9-trimethyl-7-methylene-1a,2,3,5a,6,7,8,9,10,10a-decahydro-1H-2,8a-methanocyclopenta[a]cyclopropa[e][10]annulen-11-one
(1aR,2S,5aS,8aS,9R,10aR)-4-(((4-methoxybenzyl)oxy)methyl)-1,1,7,9-tetramethyl-1,1a,2,3,5a,9,10,10a-octahydro-6H-2,8a-methanocyclopenta[a]cyclopropa[e][10]annulene-6,11-dione
(1aS,1bS,4aS,5R,6aR,7aR,8S,9aS)-1b-hydroxy-9a-(((4-methoxybenzyl)oxy)methyl)-3,5,7,7-tetramethyl-1a,1b,5,6,6a,7,7a,8,9,9a-decahydro-2H-4a,8-methanocyclopenta[3,4]cyclopropa[7,8]cyclodeca[1,2-b]oxirene-2,10-dione
(1aR,2S,5aR,8aS,9R,10aR)-5a-hydroxy-4-(((4-methoxybenzyl)oxy)methyl)-1,1,7,9-tetramethyl-1,1a,2,3,5a,9,10,10a-octahydro-6H-2,8a-methanocyclopenta[a]cyclopropa[e][10]annulene-6,11-dione
(2aS,5aR,5bR,6aS,8S,8aR,9aR,11R,11aS)-6a-(((4-methoxybenzyl)oxy)methyl)-2,4,4,9,9,11-hexamethyl-5b,6a,8,8a,9,9a,10,11-octahydro-2aH,7H-8,11a-methanocyclopropa[5',6']oxireno[2'',3'':9',10']cyclodeca[1',2':1,5]cyclopenta[1,2-d][1,3]dioxol-12-one
