百科

(3R,4R,5R)-3-((R)-Benzo[1,3]dioxol-5-yl-hydroxy-methyl)-4-hydroxy-5-trityloxymethyl-dihydro-furan-2-one

(3R,4R,5R)-3-((R)-Benzo[1,3]dioxol-5-yl-hydroxy-methyl)-4-hydroxy-5-trityloxymethyl-dihydro-furan-2-one

CAS号：302605-79-4

英文名：(3R,4R,5R)-3-((R)-Benzo[1,3]dioxol-5-yl-hydroxy-methyl)-4-hydroxy-5-trityloxymethyl-dihydro-furan-2-one

分子式：C32H28O7

分子量：524.561

合成路线

(2R,3R,4R)-2,3-dihydroxy-5-trityloxy-4-pentanolide

(2R,3R,4R)-2,3-dihydroxy-5-trityloxy-4-pentanolide

(3R,4R,5R)-3-((R)-Benzo[1,3]dioxol-5-yl-hydroxy-methyl)-4-hydroxy-5-trityloxymethyl-dihydro-furan-2-one

(3R,4R,5R)-3-((R)-Benzo[1,3]dioxol-5-yl-hydroxy-methyl)-4-hydroxy-5-trityloxymethyl-dihydro-furan-2-one

5-O-trityl-α-L-arabinose

5-O-trityl-α-L-arabinose

(3R,4R,5R)-3-((R)-Benzo[1,3]dioxol-5-yl-hydroxy-methyl)-4-hydroxy-5-trityloxymethyl-dihydro-furan-2-one

(3R,4R,5R)-3-((R)-Benzo[1,3]dioxol-5-yl-hydroxy-methyl)-4-hydroxy-5-trityloxymethyl-dihydro-furan-2-one

(2R,3S,4R)-3-hydroxy-2-phenoxythiocarbonyloxy-5-trityloxy-4-pentanolide

(2R,3S,4R)-3-hydroxy-2-phenoxythiocarbonyloxy-5-trityloxy-4-pentanolide

(3R,4R,5R)-3-((R)-Benzo[1,3]dioxol-5-yl-hydroxy-methyl)-4-hydroxy-5-trityloxymethyl-dihydro-furan-2-one

(3R,4R,5R)-3-((R)-Benzo[1,3]dioxol-5-yl-hydroxy-methyl)-4-hydroxy-5-trityloxymethyl-dihydro-furan-2-one

上游原料

(2R,3R,4R)-2,3-dihydroxy-5-trityloxy-4-pentanolide (2R,3S,4R)-3-hydroxy-2-phenoxythiocarbonyloxy-5-trityloxy-4-pentanolide 5-O-trityl-α-L-arabinose

下游产品

(2S,3R,4S)-4-methoxymethoxy-2-(3,4-methylenedioxyphenyl)-3-pivaloyloxymethyltetrahydrofuran (1R,2R,3S)-3-methoxymethoxy-1-(3,4-methylenedioxyphenyl)-2-pivaloyloxymethyl-1,4-butanediol (2R,3R,4R,5R)-2,4-bis(methoxymethoxy)-4-(3,4-methylenedioxyphenyl)-3-pivaloyloxymethylbutanal (2S,3R,4S)-3-hydroxymethyl-4-methoxymethoxy-2-(3,4-methylenedioxyphenyl)tetrahydrofuran (2R,3R,4R,5R)-3,5-bis(methoxymethoxy)-5-(3,4-methylenedioxyphenyl)-4-pivaloyloxymethyl-1-trityloxy-2-pentanol (2S,3S,4S)-4-hydroxy-3-hydroxymethyl-2-(3,4-methylenedioxyphenyl)tetrahydrofuran (2S,3S,4S)-3-(tert-butyldiphenylsilyloxy)methyl-4-hydroxy-2-(3,4-methylenedioxyphenyl)tetrahydrofuran (2R,3R,4R,5R)-3,5-bis(methoxymethoxy)-5-(3,4-methylenedioxyphenyl)-4-pivaloyloxymethyl-1,2-pentanediol (2S,3R,4R)-4-benzyl-3-(tert-butyldiphenylsilyloxy)methyl-4-hydroxy-2-(3,4-methylenedioxyphenyl)tetrahydrofuran