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(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

CAS号：303053-00-1

英文名：(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

分子式：C26H46O5

分子量：438.64

合成路线

(4R,5S)-1-iodo-4,5-isopropylidenedioxypentadecane

(4R,5S)-1-iodo-4,5-isopropylidenedioxypentadecane

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,9S,12R,13S)-9-imidazolylthiocarbonyloxy-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,9S,12R,13S)-9-imidazolylthiocarbonyloxy-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

ethyl (4E)-8-benzyloxy-4-enoctanoate

ethyl (4E)-8-benzyloxy-4-enoctanoate

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5S)-(isopropylidenedioxy)pentadecan-1-ol

(4R,5S)-(isopropylidenedioxy)pentadecan-1-ol

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,12R,13S)-5-hydroxytricosa-8,9-isopropylidenedioxy-8-en-1,4-olide

(4R,5R,12R,13S)-5-hydroxytricosa-8,9-isopropylidenedioxy-8-en-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,9S,12R,13S)-9-hydroxy-12,13-isopropylidenedioxy-5,8-oxidotricosa-1,4-olide

(4R,5R,8R,9S,12R,13S)-9-hydroxy-12,13-isopropylidenedioxy-5,8-oxidotricosa-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R)-8-benzyloxy-5-(tert-butyldiphenylsilyloxy)octan-1,4-olide

(4R,5R)-8-benzyloxy-5-(tert-butyldiphenylsilyloxy)octan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(cis,4R,5R,12R,13S)-5-tert-butyldiphenylsilyloxytricosa-12,13-isopropylidenedioxy-8-en-1,4-olide

(cis,4R,5R,12R,13S)-5-tert-butyldiphenylsilyloxytricosa-12,13-isopropylidenedioxy-8-en-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

(4R,5R,8R,12R,13S)-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide

上游原料

(4R,5S)-1-iodo-4,5-isopropylidenedioxypentadecane (4R,5S)-(isopropylidenedioxy)pentadecan-1-ol (4R,5R)-8-benzyloxy-5-(tert-butyldiphenylsilyloxy)octan-1,4-olide (4R,5R,12R,13S)-5-hydroxytricosa-8,9-isopropylidenedioxy-8-en-1,4-olide (4R,5R,8R,9S,12R,13S)-9-hydroxy-12,13-isopropylidenedioxy-5,8-oxidotricosa-1,4-olide (4R,5R,8R,9S,12R,13S)-9-imidazolylthiocarbonyloxy-12,13-isopropylidenedioxy-5,8-oxidotricosan-1,4-olide (cis,4R,5R,12R,13S)-5-tert-butyldiphenylsilyloxytricosa-12,13-isopropylidenedioxy-8-en-1,4-olide ethyl (4E)-8-benzyloxy-4-enoctanoate

下游产品

(4R,5R,8R)-5,8-oxido-12-oxotricosan-1,4-olide (2R,2'R,5'S)-5'-((4R,5S)-4,5-Dihydroxy-pentadecyl)-tetrahydro-[2,2']bifuranyl-5-one