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1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,6R)-3-hydroxy-6-hydroxymethyl-2-methyl-tetrahydro-pyran-2-yl)-propan-1-one
CAS号:304465-93-8
英文名:1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,6R)-3-hydroxy-6-hydroxymethyl-2-methyl-tetrahydro-pyran-2-yl)-propan-1-one
分子式:C18H31BrO5
分子量:407.34
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合成路线
240415-18-3
{(2R,3R)-3-[(R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-butyl]-2-methyl-oxiranyl}-methanol
304465-93-8
1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,6R)-3-hydroxy-6-hydroxymethyl-2-methyl-tetrahydro-pyran-2-yl)-propan-1-one
240133-62-4
(E)-(R)-7-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-2-enoic acid ethyl ester
304465-93-8
1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,6R)-3-hydroxy-6-hydroxymethyl-2-methyl-tetrahydro-pyran-2-yl)-propan-1-one
240133-69-1
(E)-(R)-7-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-2-en-1-ol
304465-93-8
1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,6R)-3-hydroxy-6-hydroxymethyl-2-methyl-tetrahydro-pyran-2-yl)-propan-1-one
304466-04-4
(R)-1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-ethane-1,2-diol
304465-93-8
1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,6R)-3-hydroxy-6-hydroxymethyl-2-methyl-tetrahydro-pyran-2-yl)-propan-1-one
上游原料
(E)-(R)-7-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-2-enoic acid ethyl ester
(R)-1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-ethane-1,2-diol
{(2R,3R)-3-[(R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-butyl]-2-methyl-oxiranyl}-methanol
(E)-(R)-7-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-2-en-1-ol
下游产品
(2R,4aR,6R,8aS)-6-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-carbaldehyde
thyrsiferyl 18,23-diacetate
Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-oxo-but-2-enyl ester
[(2R,4aR,6R,8aS)-6-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-methanol
Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester