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Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

CAS号：304466-00-0

英文名：Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

分子式：C33H53BrO9

分子量：673.673

合成路线

(E)-(R)-7-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-2-en-1-ol

(E)-(R)-7-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-2-en-1-ol

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

(R)-1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-ethane-1,2-diol

(R)-1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-ethane-1,2-diol

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

(2S,3S)-1-O-benzyl-2,3-epoxygeraniol

(2S,3S)-1-O-benzyl-2,3-epoxygeraniol

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

(2S,3R)-1-(benzyloxy)-3,7-dimethyloct-6-ene-2,3-diol

(2S,3R)-1-(benzyloxy)-3,7-dimethyloct-6-ene-2,3-diol

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

(E)-(R)-7-Benzyloxy-6-hydroxy-2-methyl-hept-2-enoic acid ethyl ester

(E)-(R)-7-Benzyloxy-6-hydroxy-2-methyl-hept-2-enoic acid ethyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

(R)-1-Benzyloxy-4-((2R,3R)-3-bromoethynyl-3-methyl-oxiranyl)-butan-2-ol

(R)-1-Benzyloxy-4-((2R,3R)-3-bromoethynyl-3-methyl-oxiranyl)-butan-2-ol

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

(2S,3R,6R)-6-Benzyloxymethyl-2-bromoethynyl-2-methyl-tetrahydro-pyran-3-ol

(2S,3R,6R)-6-Benzyloxymethyl-2-bromoethynyl-2-methyl-tetrahydro-pyran-3-ol

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (1S,2R)-1-benzyloxymethyl-2-hydroxy-2,6-dimethyl-hept-5-enyl ester

Acetic acid (1S,2R)-1-benzyloxymethyl-2-hydroxy-2,6-dimethyl-hept-5-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

((2S,3R,6R)-6-Benzyloxymethyl-2-bromoethynyl-2-methyl-tetrahydro-pyran-3-yloxy)-triethyl-silane

((2S,3R,6R)-6-Benzyloxymethyl-2-bromoethynyl-2-methyl-tetrahydro-pyran-3-yloxy)-triethyl-silane

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,6R)-3-hydroxy-6-hydroxymethyl-2-methyl-tetrahydro-pyran-2-yl)-propan-1-one

1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,6R)-3-hydroxy-6-hydroxymethyl-2-methyl-tetrahydro-pyran-2-yl)-propan-1-one

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-hydroxy-but-2-enyl ester

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上游原料

(2S,3S)-1-O-benzyl-2,3-epoxygeraniol (R)-1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-ethane-1,2-diol ((2S,3R,6R)-6-Benzyloxymethyl-2-bromoethynyl-2-methyl-tetrahydro-pyran-3-yloxy)-triethyl-silane {(2R,3R)-3-[(R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-butyl]-2-methyl-oxiranyl}-methanol [(2R,4aR,6R,8aS)-6-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-methanol (E)-(R)-7-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-2-en-1-ol (R)-1-Benzyloxy-4-((2R,3R)-3-bromoethynyl-3-methyl-oxiranyl)-butan-2-ol (2S,3R,6R)-6-Benzyloxymethyl-2-bromoethynyl-2-methyl-tetrahydro-pyran-3-ol (E)-(R)-7-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hept-2-enoic acid ethyl ester {(R)-1-Benzyloxymethyl-3-[(2R,3R)-3-(2,2-dibromo-vinyl)-3-methyl-oxiranyl]-propoxy}-tert-butyl-dimethyl-silane (E)-(R)-7-Benzyloxy-6-hydroxy-2-methyl-hept-2-enoic acid ethyl ester (2S,3R)-3-[(R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-butyl]-2-methyl-oxirane-2-carbaldehyde (R)-1-((2S,5R)-5-bromo-2,6,6-trimethyltetrahydro-2H-pyran-2-yl)ethane-1,2-diyl dibenzoate 1-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,6R)-3-hydroxy-6-hydroxymethyl-2-methyl-tetrahydro-pyran-2-yl)-propan-1-one Acetic acid (1S,2R)-1-benzyloxymethyl-2-hydroxy-2,6-dimethyl-hept-5-enyl ester (2S,3R)-1-(benzyloxy)-3,7-dimethyloct-6-ene-2,3-diol

下游产品

venustatriol-18-acetate Acetic acid (S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-oxo-butyl ester thyrsiferyl 18,23-diacetate Acetic acid (E)-(S)-1-[(2R,5R)-5-(1-acetoxy-1-methyl-ethyl)-2-methyl-tetrahydro-furan-2-yl]-4-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-oxo-but-2-enyl ester