百科

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

CAS号：304671-94-1

英文名：(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

分子式：C34H41IO7

分子量：688.59

合成路线

methyl 4,6-O-benzylidene-3-O-benzyl-α-D-glucopyranoside

methyl 4,6-O-benzylidene-3-O-benzyl-α-D-glucopyranoside

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

(2R,4aR,6S,7S,8S,8aR)-7-Allyl-8-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2R,4aR,6S,7S,8S,8aR)-7-Allyl-8-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

((2R,3R,4S,5S,6S)-5-Allyl-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanol

((2R,3R,4S,5S,6S)-5-Allyl-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanol

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

(2R,4aR,6S,7S,8S,8aR)-7-Allyl-7,8-bis-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

(2R,4aR,6S,7S,8S,8aR)-7-Allyl-7,8-bis-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

(2S,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-6-iodomethyl-2-methoxy-tetrahydro-pyran

上游原料

methyl 4,6-O-benzylidene-3-O-benzyl-α-D-glucopyranoside (2R,4aR,6S,7S,8S,8aR)-7-Allyl-8-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol ((2R,3R,4S,5S,6S)-5-Allyl-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanol (2R,4aR,6S,7S,8S,8aR)-7-Allyl-7,8-bis-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

下游产品

(2S,3S,4S,5S)-3,4,5-Tris-benzyloxy-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-2-methoxy-6-methylene-tetrahydro-pyran (2S,3S,4R)-2,3,4-Tris-benzyloxy-4-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-5-hydroxy-cyclohexanone