百科

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

CAS号：305791-09-7

英文名：(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

分子式：C34H57N3O12

分子量：699.829

合成路线

D-Galactopyranoside, 2-propenyl

D-Galactopyranoside, 2-propenyl

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2S,3S,4Z)-2-hydroxy-3-methoxymethoxy-5-dimethylphenylsilyl-octadec-4-en-1-yl] 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

(+)-1-O-[(2S,3S,4Z)-2-hydroxy-3-methoxymethoxy-5-dimethylphenylsilyl-octadec-4-en-1-yl] 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4Z)-2-azido-3-methoxymethoxy-5-dimethylphenylsilyl-octadec-4-en-1-yl] 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4Z)-2-azido-3-methoxymethoxy-5-dimethylphenylsilyl-octadec-4-en-1-yl] 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

2-oxoethyl 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

2-oxoethyl 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

1-O-allyl 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

1-O-allyl 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

((5S,6S)-2,2-dimethyl-5-methoxymethoxy-3-tridecyl-5,6-dihydro-2H-1,2-oxasilin-6-yl)methyl 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

((5S,6S)-2,2-dimethyl-5-methoxymethoxy-3-tridecyl-5,6-dihydro-2H-1,2-oxasilin-6-yl)methyl 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

1-O-((2S,3S)-2-hydroxy-3-methoxymethoxy-4-penten-1-yl) 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

1-O-((2S,3S)-2-hydroxy-3-methoxymethoxy-4-penten-1-yl) 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

(+)-1-O-[(2R,3S,4E)-2-azido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

上游原料

(+)-1-O-[(2S,3S,4Z)-2-hydroxy-3-methoxymethoxy-5-dimethylphenylsilyl-octadec-4-en-1-yl] 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside (+)-1-O-[(2R,3S,4Z)-2-azido-3-methoxymethoxy-5-dimethylphenylsilyl-octadec-4-en-1-yl] 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside 1-O-allyl 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside ((5S,6S)-2,2-dimethyl-5-methoxymethoxy-3-tridecyl-5,6-dihydro-2H-1,2-oxasilin-6-yl)methyl 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside 2-oxoethyl 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside 1-O-((2S,3S)-2-hydroxy-3-methoxymethoxy-4-penten-1-yl) 2,3,4,6-tetra-O-tert-butyldimethylsilyl-β-D-glucopyranoside

下游产品

(+)-1-O-[(2R,3S,4E)-2-n-hexadecanamido-3-methoxymethoxy-octadec-4-en-1-yl] 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside Hexadecanoic acid [(E)-(1R,2S)-2-hydroxy-1-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxymethyl)-heptadec-3-enyl]-amide