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methyl (1S,3R)-3-[(tert-butyldimethylsilyl)oxy]-2,2-dimethyl-6-oxo-cyclohexanecarboxylate

methyl (1S,3R)-3-[(tert-butyldimethylsilyl)oxy]-2,2-dimethyl-6-oxo-cyclohexanecarboxylate

CAS号：309243-65-0

英文名：methyl (1S,3R)-3-[(tert-butyldimethylsilyl)oxy]-2,2-dimethyl-6-oxo-cyclohexanecarboxylate

分子式：C16H30O4Si

分子量：314.493

合成路线

4-acetoxy-3-methyl-2-cyclohexen-1-one

4-acetoxy-3-methyl-2-cyclohexen-1-one

methyl (1S,3R)-3-[(tert-butyldimethylsilyl)oxy]-2,2-dimethyl-6-oxo-cyclohexanecarboxylate

methyl (1S,3R)-3-[(tert-butyldimethylsilyl)oxy]-2,2-dimethyl-6-oxo-cyclohexanecarboxylate

(R)-4-hydroxy-3-methyl-cyclohex-2-en-1-one

(R)-4-hydroxy-3-methyl-cyclohex-2-en-1-one

methyl (1S,3R)-3-[(tert-butyldimethylsilyl)oxy]-2,2-dimethyl-6-oxo-cyclohexanecarboxylate

methyl (1S,3R)-3-[(tert-butyldimethylsilyl)oxy]-2,2-dimethyl-6-oxo-cyclohexanecarboxylate

上游原料

4-acetoxy-3-methyl-2-cyclohexen-1-one (R)-4-hydroxy-3-methyl-cyclohex-2-en-1-one

下游产品

(-)-Karahana lactone (1S,5R)-cis-3-hydroxy-2,2-dimethyl-6-methylenecyclohexanemethanol (1R,5R)-(-)-8,8-dimethyl-6-oxabicyclo<3.2.1>octane-2,7-dione