百科

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

CAS号：312493-81-5

英文名：(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

分子式：C28H34O5

分子量：450.567

合成路线

312493-66-6

(4aS,6S,7R,8aS,9aR,10aR)-2,2,4a-Trimethyl-7-((E)-styryl)-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312308-12-6

(4aS,6R,7S,8aR)-6-Hydroxymethyl-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312493-64-4

{(2S,3S)-3-[(4aS,6R,7S,8aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-ylmethyl]-oxiranyl}-methanol

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312493-62-2

Trifluoro-methanesulfonic acid (4aS,6R,7S,8aR)-7-(tert-butyl-dimethyl-silanyloxy)-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-ylmethyl ester

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312493-77-9

(E)-4-[(4aS,6R,7S,8aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-but-2-en-1-ol

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312493-67-7

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-hydroxymethyl-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312493-78-0

(4aS,6S,7R,8aS,9aR,10aR)-6-Benzyloxy-2,2,4a-trimethyl-7-((E)-styryl)-octahydro-1,3,8,10-tetraoxa-anthracene

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312493-80-4

(R)-1-[(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-2-yl]-but-3-en-1-ol

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312493-65-5

tert-Butyl-dimethyl-{(4aS,6R,7S,8aR)-2,2,4a-trimethyl-6-[(2S,3S)-3-((E)-styryl)-oxiranylmethyl]-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy}-silane

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

312493-68-8

[(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-2-yl]-methanol

312493-81-5

(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-((R)-1-hydroxy-but-3-enyl)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol

上游原料

(4aS,6S,7R,8aS,9aR,10aR)-6-Benzyloxy-2,2,4a-trimethyl-7-((E)-styryl)-octahydro-1,3,8,10-tetraoxa-anthracene 4-[(4aS,6R,7S,8aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-but-2-yn-1-ol Trifluoro-methanesulfonic acid (4aS,6R,7S,8aR)-7-(tert-butyl-dimethyl-silanyloxy)-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-ylmethyl ester (4aS,6R,7S,8aR)-6-Hydroxymethyl-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol (R)-1-[(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-2-yl]-but-3-en-1-ol [(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-2-yl]-methanol (E)-4-[(4aS,6R,7S,8aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-but-2-en-1-ol (2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-2-hydroxymethyl-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-3-ol (4aS,6S,7R,8aS,9aR,10aR)-2,2,4a-Trimethyl-7-((E)-styryl)-octahydro-1,3,8,10-tetraoxa-anthracen-6-ol tert-Butyl-dimethyl-{(4aS,6R,7S,8aR)-2,2,4a-trimethyl-6-[(2S,3S)-3-((E)-styryl)-oxiranylmethyl]-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy}-silane {(2S,3S)-3-[(4aS,6R,7S,8aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2,4a-trimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-ylmethyl]-oxiranyl}-methanol

下游产品

(R)-4-[(2S,3R,4aS,6R,7S,8aR)-7-Benzyloxy-3-hydroxy-2-methyl-6-((E)-styryl)-octahydro-pyrano[3,2-b]pyran-2-yl]-butane-1,2,4-triol (2R,4S,4aS,6S,7R,8aS,9aR,10aR)-6-Benzyloxy-2-(2-hydroxymethyl-allyl)-4a-methyl-7-((E)-styryl)-decahydro-1,8,10-trioxa-anthracen-4-ol (4R,4aS,6S,7R,8aS,9aR,10aR)-6-Benzyloxy-2-methoxy-4a-methyl-7-((E)-styryl)-decahydro-1,8,10-trioxa-anthracen-4-ol