百科

(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

CAS号：312695-81-1

英文名：(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

分子式：C30H50O5Si

分子量：518.801

合成路线

273733-89-4

(4S,6R)-7-(benzyloxy)-6-methylhept-1-en-4-ol

312695-81-1

(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

259199-01-4

{(2R)-6-[3-(4-methoxybenzyloxy)-2-methyl-propyl]-(2R,6S)-5,6-dihydro-2H-pyran-2-yl}acetaldehyde

312695-81-1

(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

527742-77-4

[4S,6R]-8-benzenesulfonyl-6-methyloct-1-en-4-ol

312695-81-1

(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

527742-78-5

[2R,6R]-6-[(2R)-(4-benzenesulfonyl-2-methylbutyl)-5,6-dihydro-2H-pyran-2-yl]ethanol

312695-81-1

(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

445306-72-9

(2R,6S)-2-{(2R)-6-[3-(4-methoxybenzyloxy)-2-methylpropyl]-5,6-dihydro-2H-pyran-2-yl}-ethanol

312695-81-1

(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

273733-91-8

(S)-6-((R)-3-(benzyloxy)-2-methylpropyl)-5,6-dihydro-2H-pyran-2-one

312695-81-1

(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

527742-94-5

(6R)-6-[(2R)-(4-benzenesulfonyl-2-methylbutyl)]-5,6-dihydro-2H-pyran-2-one

312695-81-1

(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

385809-13-2

[2R,(2R),6R]-{2-[6-(4-benzenesulfonyl-2-methylbutyl)-5,6-dihydro-2H-pyran-2-yl]ethoxy}-tert-butyldimethylsilane

312695-81-1

(2S,6S)-7-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,6-dihydro-2H-pyran-2-yl}-1-(4-methoxy-benzyloxy)-6-methyl-4-methylene-heptan-2-ol

上游原料

(4S,6R)-7-(benzyloxy)-6-methylhept-1-en-4-ol [2R,6R]-6-[(2R)-(4-benzenesulfonyl-2-methylbutyl)-5,6-dihydro-2H-pyran-2-yl]ethanol (6R)-6-[(2R)-(4-benzenesulfonyl-2-methylbutyl)]-5,6-dihydro-2H-pyran-2-one [4S,6R]-8-benzenesulfonyl-6-methyloct-1-en-4-ol {(2R)-6-[3-(4-methoxybenzyloxy)-2-methyl-propyl]-(2R,6S)-5,6-dihydro-2H-pyran-2-yl}acetaldehyde (S)-6-((R)-3-(benzyloxy)-2-methylpropyl)-5,6-dihydro-2H-pyran-2-one (2R,6S)-2-{(2R)-6-[3-(4-methoxybenzyloxy)-2-methylpropyl]-5,6-dihydro-2H-pyran-2-yl}-ethanol [2R,(2R),6R]-{2-[6-(4-benzenesulfonyl-2-methylbutyl)-5,6-dihydro-2H-pyran-2-yl]ethoxy}-tert-butyldimethylsilane

下游产品

C.2-C.3-(E) des-epoxy-laulimalide 16,17-deoxy-laulimalide (3Z,9E)-(1R,7S,11S,15S,17R)-11-Methoxymethoxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one