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(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
CAS号:321667-30-5
英文名:(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
分子式:C25H42O6
分子量:438.597
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合成路线
488721-37-5
{(2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(E)-(2R,4R,5S,10R)-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,4,10-trihydroxy-5-methyl-dec-8-enyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
947321-44-0
2-((2S,4S,6R)-4-bromo-6-((S)-2-methoxy-3-((2R,3S,6S)-3-methyl-6-((S,E)-6-methyl-2-((triisopropylsilyl)oxy)hept-3-en-1-yl)tetrahydro-2H-pyran-2-yl)propyl)tetrahydro-2H-pyran-2-yl)acetaldehyde
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
618096-63-2
(1R,3R,5R,9R,13R,15S,18S)-3-methoxy-18-methyl-13-<(E)-4-methylpent-1-enyl>-12,19,20-trioxatricyclo<13.3.1.15,9>icosane-7,11-dione
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
477974-86-0
(1R,3S,5S,7S,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
488721-44-4
5-((3-methylbutyl)sulfonyl)-1-phenyl-1H-tetrazole
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
637002-76-7
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-oxo-hex-2-enoic acid methyl ester
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
488721-28-4
[(2R,4S,6S)-4-Hydroxy-6-((E)-propenyl)-tetrahydro-pyran-2-yl]-acetic acid ethyl ester
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
488721-32-0
Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-methyl-7-triisopropylsilanyloxy-hept-2-enyl ester
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
187218-77-5
6-[2-(tert-butyldimethylsilanyloxy)ethyl]-5-methyltetrahydropyran-2-one
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
321667-25-8
((2R,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-{(S)-3-[(2R,3S,6S)-6-((E)-(R)-2-hydroxy-6-methyl-hept-3-enyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methoxy-propyl}-tetrahydro-pyran-2-yl)-acetic acid methyl ester
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
488721-38-6
[4-(tert-butyl-dimethyl-silanyloxy)-6-(3-{6-[2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-1-(2,4,6-triisopropyl-phenylselanyl)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-2-hydroxy-propyl)-tetrahydro-pyran-2-yl]-acetic acid methyl ester
321667-30-5
(1R,3S,5S,7R,9R,13R,15S,18S)-7-hydroxy-3-methoxy-18-methyl-13-((E)-4-methylpent-1-enyl)-12,19,20-trioxatricyclo[13.3.1.15,9]icosan-11-one
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上游原料
(E)-(S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-oxo-hex-2-enoic acid methyl ester
(1R,3R,5R,9R,13R,15S,18S)-3-methoxy-18-methyl-13-<(E)-4-methylpent-1-enyl>-12,19,20-trioxatricyclo<13.3.1.15,9>icosane-7,11-dione
2-{6-[2-(tert-butyldimethylsilanyloxy)-6-methylhept-3-enyl]-3-methyltetrahydropyran-2-yl}ethanol
(R)-2-(4-Methoxy-phenyl)-4-((S)-1-methyl-allyl)-[1,3]dioxane
2,4,6-trimethylbenzenesulfonic acid (2R,6S)-6-((R)-4-benzyloxy-2-methoxybutyl)-5,6-dihydro-2H-pyran-2-ylmethyl ester
((2R,4R,6R)-4-(tert-Butyl-diphenyl-silanyloxy)-6-{(S)-3-[(2R,3S,6S)-6-((E)-(R)-2-hydroxy-6-methyl-hept-3-enyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methoxy-propyl}-tetrahydro-pyran-2-yl)-acetic acid methyl ester
(2E,8E)-(5S,7S)-5,7-Dihydroxy-deca-2,8-dienoic acid ethyl ester
2-((2S,4S,6R)-4-bromo-6-((S)-2-methoxy-3-((2R,3S,6S)-3-methyl-6-((S,E)-6-methyl-2-((triisopropylsilyl)oxy)hept-3-en-1-yl)tetrahydro-2H-pyran-2-yl)propyl)tetrahydro-2H-pyran-2-yl)acetaldehyde
acrylic acid 1-[2-(tert-butyldimethylsilanyloxy)ethyl]-2-methylbut-3-enyl ester
(S)-1-((2R,3S,6S)-6-((R,E)-2-((tert-butyldimethylsilyl)oxy)-6-methylhept-3-en-1-yl)-3-methyltetrahydro-2H-pyran-2-yl)pent-4-en-2-ol
6-[2-(tert-butyldimethylsilanyloxy)ethyl]-5-methyltetrahydropyran-2-one
5-((3-methylbutyl)sulfonyl)-1-phenyl-1H-tetrazole
(5S,6R)-6-((S)-2-Methoxy-3-{(2R,4S,6S)-6-[2-(4-methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-propyl)-5-methyl-tetrahydro-pyran-2-one
[(2R,4S,6S)-4-Hydroxy-6-((E)-propenyl)-tetrahydro-pyran-2-yl]-acetic acid ethyl ester
(2S,4S,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-[2-(4-methoxy-benzyloxy)-ethyl]-tetrahydro-pyran-4-ol
(2-((2S,4S,6R)-6-((S)-3-((2R,3S,6S)-6-(2-(benzyloxy)ethyl)-3-methyltetrahydro-2H-pyran-2-yl)-2-methoxypropyl)-4-((tert-butyldimethylsilyl)oxy)tetrahydro-2H-pyran-2-yl)ethoxy)(tert-butyl)dimethylsilane
(E)-(2R,3S)-3-(Dimethyl-phenyl-silanyl)-2-hydroxy-hex-4-enoic acid isopropyl ester
Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-methyl-7-triisopropylsilanyloxy-hept-2-enyl ester
(E)-(5S,7R,9S)-5-(tert-Butyl-dimethyl-silanyloxy)-10-{(2R,3S,6S)-6-[(E)-(R)-2-(tert-butyl-dimethyl-silanyloxy)-6-methyl-hept-3-enyl]-3-methyl-tetrahydro-pyran-2-yl}-7,9-dihydroxy-dec-2-enoic acid methyl ester
Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-6-methyl-hept-2-enyl ester
Benzoic acid (E)-(1R,6S,7R,9R)-10-[(2R,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-ethoxycarbonylmethyl-tetrahydro-pyran-2-yl]-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7,9-dihydroxy-6-methyl-dec-2-enyl ester
{(2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(E)-(2R,4R,5S,10R)-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,4,10-trihydroxy-5-methyl-dec-8-enyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester
1-{(2S,4S,6S)-6-[2-(4-Methoxy-benzyloxy)-ethyl]-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl}-propan-2-one
(2R,6S)-2-{(S)-3-[(2R,3S,6S)-6-(2-Benzyloxy-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methoxy-propyl}-6-(2-triisopropylsilanyloxy-ethyl)-tetrahydro-pyran-4-one
9-{6-[2-(tert-butyldimethylsilanyloxy)-6-methylhept-3-enyl]-3-methyltetrahydropyran-2-yl}-8-methoxynon-1-ene-4,6-diol
[(2R,4R,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(2-oxo-propyl)-tetrahydro-pyran-2-yl]-acetic acid ethyl ester
(2S,4S,6S)-2-{(S)-3-[(2R,3S,6S)-6-(2-Benzyloxy-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methoxy-propyl}-6-(2-triisopropylsilanyloxy-ethyl)-tetrahydro-pyran-4-ol
(3R,4S)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol
[4-(tert-butyl-dimethyl-silanyloxy)-6-(3-{6-[2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-1-(2,4,6-triisopropyl-phenylselanyl)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-2-hydroxy-propyl)-tetrahydro-pyran-2-yl]-acetic acid methyl ester
下游产品
5-[2-(3-Methoxycarbonylamino-prop-1-ynyl)-oxazol-4-yl]-pent-2-ynoic acid (1R,3S,5R,7R,9R,13R,15S,18S)-3-methoxy-18-methyl-13-((E)-4-methyl-pent-1-enyl)-11-oxo-12,19,20-trioxa-tricyclo[13.3.1.15,9]icos-7-yl ester