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2,3,4,6-四-O-三甲基硅-D-吡喃葡萄糖酸-1,5-内酯

2,3,4,6-四-O-三甲基硅-D-吡喃葡萄糖酸-1,5-内酯

CAS号：32384-65-9

英文名：(3R,4S,5R,6R)-3,4,5-tris(trimethylsilyloxy)-6-(trimethylsilyloxymethyl)oxan-2-one

分子式

C18H42O6Si4

熔点

密度

分子量

466.864

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

2,3,4,6-四-O-三甲基硅-D-吡喃葡萄糖酸-1,5-内酯

英文名称

(3R,4S,5R,6R)-3,4,5-tris(trimethylsilyloxy)-6-(trimethylsilyloxymethyl)oxan-2-one

中文别名

2,3,4,6-四-O-三甲基硅基-D-葡萄糖酸内酯

英文别名

(3R,4S,5R,6R)-3,4,5-tris(trimethylsilyloxy)-6-((trimethylsilyloxy)methyl)tetrahydro-2H-pyran-2-one、2,3,4,6-tetrakis-O-trimethylsilyl-D-glucono-1,5-lactone、(3R,4S,5R,6R)-3,4,5-tris(trimethylsilyloxy)-6-(trimethylsilyloxymethyl)tetrahydropyran-2-one

CAS号

32384-65-9

分子式

C18H42O6Si4

分子量

466.864

精确质量

466.206

PSA

63.22

LOGP

4.4236

编号系统

EINECS号

608-732-8

生产方法及用途

用途

达格列净中间体。

下游产品

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(2R,3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-ethylcyclopentyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)2methoxytetrahydro-2H-pyran-3,4,5-triol

(2R,3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-ethylcyclopentyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)2methoxytetrahydro-2H-pyran-3,4,5-triol

(3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-(trifluoromethyl)cyclobutyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol

(3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-(trifluoromethyl)cyclobutyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol

(2S,3R,4S,5S,6R)2-(4-chloro-3-(4-((1-ethylcyclopentyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol

(2S,3R,4S,5S,6R)2-(4-chloro-3-(4-((1-ethylcyclopentyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol

(2S,3R,4R,5S,6R)-2-(4-chloro-3-(4-((1-(trifluoromethyl)cyclopropyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

(2S,3R,4R,5S,6R)-2-(4-chloro-3-(4-((1-(trifluoromethyl)cyclopropyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

2-(2-chloro-5-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)benzyl)-6-methyl-[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one

2-(2-chloro-5-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)benzyl)-6-methyl-[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one

(2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-chloro-3-(4-((1-(trifluoromethyl)cyclopropyl)methoxy)benzyl)phenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate

(2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-chloro-3-(4-((1-(trifluoromethyl)cyclopropyl)methoxy)benzyl)phenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate

下游产品

(2R,3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-ethylcyclopentyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)2methoxytetrahydro-2H-pyran-3,4,5-triol (3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-(trifluoromethyl)cyclobutyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol (2S,3R,4S,5S,6R)2-(4-chloro-3-(4-((1-ethylcyclopentyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol (2S,3R,4R,5S,6R)-2-(4-chloro-3-(4-((1-(trifluoromethyl)cyclopropyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol 2-(2-chloro-5-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)benzyl)-6-methyl-[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-chloro-3-(4-((1-(trifluoromethyl)cyclopropyl)methoxy)benzyl)phenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate (2S,3R,4R,5S,6R)-2-(4-fluoro-3-(4-((1-(trifluoromethyl)cyclopropyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol 2-chloro-5-(1-methoxy-2,3,4,6-tetra-O-acetyl-D-glucopyranosyl)phenyl 5-bromo-2-thienyl ketone 1,1-anhydro-1-C-<2-(hydroxymethyl)-4,6-dimethoxyphenyl>-β-D-glucopyranose (2S,3R4R5S,6R)-2-(3-(4-((4,4-difluoro-1-methylcyclohexyl)methoxy)benzyl)-4-fluorophenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-chloro-3-(4-((4,4-difluoro-1-methylcyclohexyl)methoxy)benzyl)phenyl)tetratydro-2H-3,4,5-triyl triacetate (3R,4S,5S,6R)-2-(3-(2-(4-ethoxyphenyl)propan-2-yl)-2-methylphenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(5-(4-(4-((1-((2-(dimethylamino)ethyl)amino)-2-methyl-1-oxopropan-2-yl)amino)-3,3-dimethyl-4-oxobut-1-en-1-yl)benzyl)-4-isopropyl-2-methoxyphenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate (2S,3R,4R,5S,6R)-2-(4-fluoro-3-(4-((1-(trifluoromethyl)cyclobutyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (2R,3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-ethylcyclohexyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol (3R,4R,5S,6R)-2-(3-(4-hydroxybenzyl)-4-methylphenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol tert-butyl 2-chloro-5-(1-methoxy-D-glucopyranosyl)benzoate (2S,3R,4R,5S,6R)-2-(4-chloro-3-(4-((1-(trifluoromethyl)cyclobutyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (2S,3R,4R,5S,6R)-2-(3-(2-(4-ethoxyphenyl)propan-2-yl)-2-methylphenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (2S,3R,4R,5S,6R)-2-(4-chloro-3-(4-((1-methylcyclopentyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-chloro-3-(hydroxymethyl)phenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate (2S,3R,4R,5S,6R)-2-(3-(4-ethylbenzyl)-(phenyl))-6-hydroxymethyl-tetrahydro-2H-pyran-3,4,5-triol L-phenylalanine (2R,3S,4R,5R,6S)-2-(hydroxymethyl)-6-(4-methyl-3-(4-((1-(trifluoromethyl)cyclobutyl)methoxy)benzyl)phenyl)tetrahydro-2H-pyran-3,4,5-triol (2S,3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-ethylcyclobutyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol (3R,4R,5S,6R)-2-(4-chloro-3-(4-((1-(trifluoromethyl)cyclobutyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (2S,3R,4S,5S,6R)-6-[(tert-butyl(dimethyl)silyl)oxy-methyl]-2-[4-chloro-3-[[4-(2,2,2-trifluoroethoxy)phenyl]methyl]phenyl]-2-methoxy-tetrahydropyran-3,4,5-triol 2-(2-chloro-5-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)benzyl)-7-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one (3R,4R,5S,6R)-2-(3-(2-(4-ethoxyphenyl)propan-2-yl)-4-methylphenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-fluoro-3-(4-((1-(trifluoromethyl)cyclopropyl)methoxy)benzyl)phenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate 2-chloro-5-(1-methoxy-2,3,4,6-tetra-O-acetyl-D-glucopyranosyl)benzoic acid O-methylglucoside (3R,4S,5S,6R)-2-(3-(4-hydroxybenzyl)-4-methylphenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol 4-chloro-1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-3-[(5-(3-pyridyl)-2-thienyl)methyl]benzene (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(3-(4-((4,4-difluoro-1-methylcyclohexyl)methoxy)benzyl)-4-fluorophenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate [[(2R,3R,4S,5R,6S)-3,4,5-tribenzyloxy-6-[4-chloro-3-[[4-(2,2,2-trifluoroethoxy)phenyl]methyl]phenyl]-6-methoxy-tetrahydropyran-2-yl]methoxy]tert-butyl-dimethyl-silane (2S,3R,4R,5S,6R)-2-(4-chloro-3-(4-((4,4-difluoro-1-methylcyclohexyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-fluoro-3-(4-((1-(trifluoromethyl)cyclobutyl)methoxy)benzyl)phenyl)tetrahydro-2H-pyran-3,4, 5-triyl triacetate (2S,3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-ethylcyclohexyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol 4-chloro-1-(β-D-glucopyranosyl)-3-[(5-(3-pyridyl)-2-thienyl)methyl]benzene 2-(2-chloro-5-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)benzyl)-6-fluoro-[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one (2S,3R,4S,5S,6R)-2-(4-chloro-3-(4-((3-ethyloxetan-3-yl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol 1-chloro-4-(β-D-glucopyranos-1-yl)-2-(4-ethynyl-benzyl)-benzene (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(3-(((tert-butyldiphenylsilyl)oxy)methyl)-4-chlorophenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate tert-butyl 2-chloro-5-(1-methoxy-2,3,4,6-tetra-O-acetyl-D-glucopyranosyl)benzoate (2S,3R,4S,5S,6R)-2-(4-chloro-3-(4-((1-methylcyclohexyl)methoxy)benzyl)phenyl)-6-(hydroxymethyl)-2-methoxytetrahydro-2H-pyran-3,4,5-triol 1-(4-(2-chloro-5-((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)benzyl)phenyl)-3-isopropylimidazolidine-2,4-dione (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-chloro-3-(4-((1-( trifluoromethyl)cyclobutyl)methoxy)benzyl)phenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate (2R,3S,4R,5R,6S)-2-(hydroxymethyl)-6-(4-methyl-3-(4-((1-(trifluoromethyl)cyclopropyl)methoxy)benzyl)phenyl)tetrahydro-2H-pyran-3,4,5-triol (2R,3R,4R,5S,6S)-2-(acetoxymethyl)-6-(4-chloro-3-(4-((1-methylcyclopentyl)methoxy)benzyl)phenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate