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(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
CAS号:325172-35-8
英文名:(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
分子式:C21H26O6
分子量:374.428
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合成路线
325172-42-7
Toluene-4-sulfonic acid (2S,3S,5S)-2-allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptyl ester
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
325172-31-4
(2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-hydroxy-7-(4-methoxy-benzyloxy)-heptan-1-one
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
325172-46-1
(E)-(7R,9S,10R)-7-(2-Hydroxy-ethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
325172-30-3
(S)-3-((tert-butyl)dimethylsilyloxy)-5-(4-methoxybenzyloxy)pentanal
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
325172-43-8
tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
325172-32-5
(2S,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-ol
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
325172-33-6
2-Allyl-6-methoxy-benzoic acid (1R,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyl ester
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
325172-41-6
(2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-one
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
325172-34-7
((E)-(7S,9S,10R)-4-Methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-acetaldehyde
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
312962-27-9
(7R,9S,10R)-4-methoxy-7-[2-(4-methoxy-benzyloxy)-ethyl]-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one
325172-35-8
(E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester
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上游原料
(3S,5S,6R)-1-(4-Methoxy-benzyloxy)-5-methoxymethoxy-6-methyl-non-8-en-3-ol
((E)-(7S,9S,10R)-4-Methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-acetaldehyde
(3R)-1-[(4-methoxybenzyl)oxy]hex-5-en-3-ol
tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane
2-Allyl-6-methoxy-benzoic acid (1R,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyl ester
(7R,9S,10R)-4-methoxy-7-[2-(4-methoxy-benzyloxy)-ethyl]-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one
Toluene-4-sulfonic acid (2S,3S,5S)-2-allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptyl ester
(2S,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-ol
(E)-(7R,9S,10R)-7-(2-Hydroxy-ethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one
(2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-one
(2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-hydroxy-7-(4-methoxy-benzyloxy)-heptan-1-one
(R)-tert-butyl(1-(4-methoxybenzyloxy)hex-5-en-3-yloxy)dimethylsilane
(S)-3-((tert-butyl)dimethylsilyloxy)-5-(4-methoxybenzyloxy)pentanal
下游产品
(E)-(7R,9S,10R)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-7-((E)-3-isocyanato-allyl)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one
(E)-4-[(E)-(7R,9S,10R)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enoic acid
(2Z,4Z)-Hepta-2,4-dienoic acid {(E)-3-[(E)-(7R,9S,10R)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-amide