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tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

CAS号：325172-43-8

英文名：tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

分子式：C26H46O5Si

分子量：466.726

合成路线

Toluene-4-sulfonic acid (2S,3S,5S)-2-allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptyl ester

Toluene-4-sulfonic acid (2S,3S,5S)-2-allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptyl ester

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

(2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-hydroxy-7-(4-methoxy-benzyloxy)-heptan-1-one

(2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-hydroxy-7-(4-methoxy-benzyloxy)-heptan-1-one

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

(3R)-1-[(4-methoxybenzyl)oxy]hex-5-en-3-ol

(3R)-1-[(4-methoxybenzyl)oxy]hex-5-en-3-ol

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

(S)-3-((tert-butyl)dimethylsilyloxy)-5-(4-methoxybenzyloxy)pentanal

(S)-3-((tert-butyl)dimethylsilyloxy)-5-(4-methoxybenzyloxy)pentanal

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

(R)-tert-butyl(1-(4-methoxybenzyloxy)hex-5-en-3-yloxy)dimethylsilane

(R)-tert-butyl(1-(4-methoxybenzyloxy)hex-5-en-3-yloxy)dimethylsilane

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

(2S,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-ol

(2S,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-ol

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

(2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-one

(2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-one

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

tert-Butyl-{(1S,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyloxy}-dimethyl-silane

上游原料

(3R)-1-[(4-methoxybenzyl)oxy]hex-5-en-3-ol Toluene-4-sulfonic acid (2S,3S,5S)-2-allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptyl ester (2S,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-ol (2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-7-(4-methoxy-benzyloxy)-3-methoxymethoxy-heptan-1-one (2R,3S,5S)-2-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-3-hydroxy-7-(4-methoxy-benzyloxy)-heptan-1-one (R)-tert-butyl(1-(4-methoxybenzyloxy)hex-5-en-3-yloxy)dimethylsilane (S)-3-((tert-butyl)dimethylsilyloxy)-5-(4-methoxybenzyloxy)pentanal

下游产品

(3S,5S,6R)-1-(4-Methoxy-benzyloxy)-5-methoxymethoxy-6-methyl-non-8-en-3-ol (E)-4-((E)-(7R,9S,10R)-4,9-Dihydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid methyl ester ((E)-(7S,9S,10R)-4-Methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-acetaldehyde (E)-(7R,9S,10R)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-7-((E)-3-isocyanato-allyl)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one 2-Allyl-6-methoxy-benzoic acid (1R,3S,4R)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyl ester (E)-4-[(E)-(7R,9S,10R)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enoic acid (E)-(7R,9S,10R)-7-(2-Hydroxy-ethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one (2Z,4Z)-Hepta-2,4-dienoic acid {(E)-3-[(E)-(7R,9S,10R)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-amide (7R,9S,10R)-4-methoxy-7-[2-(4-methoxy-benzyloxy)-ethyl]-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one