(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

CAS号：326599-42-2

英文名：(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

分子式：C23H28O2Si

分子量：364.553

合成路线

(1S,3S,5R)-3-acetoxy-5-hydroxy-1-(methoxycarbonyl)cyclohexane

(1S,3S,5R)-3-acetoxy-5-hydroxy-1-(methoxycarbonyl)cyclohexane

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

[(1S,3R,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-yl]-methanol

[(1S,3R,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-yl]-methanol

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

methyl (1R,3S,5R)-3-hydroxy-5-tosyloxycyclohexanecarboxylate

methyl (1R,3S,5R)-3-hydroxy-5-tosyloxycyclohexanecarboxylate

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

Methyl (1R,3S,5R)-3-acetoxy-5-tosyloxy-cyclohexanecarboxylate

Methyl (1R,3S,5R)-3-acetoxy-5-tosyloxy-cyclohexanecarboxylate

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

methyl(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]-hexane-3a-carboxylate

methyl(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]-hexane-3a-carboxylate

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

methyl (1R,3S,5R)-3-tert-(butyldiphenylsilyloxy)-5-tosyloxycyclohexanecarboxylate

methyl (1R,3S,5R)-3-tert-(butyldiphenylsilyloxy)-5-tosyloxycyclohexanecarboxylate

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]hexane-3a-carbaldehyde

上游原料

methyl (1R,3S,5R)-3-tert-(butyldiphenylsilyloxy)-5-tosyloxycyclohexanecarboxylate methyl(2R,3aS,4aS)-2-(tert-butyldiphenylsilyloxy)bicyclo[3.1.0]-hexane-3a-carboxylate (1S,3S,5R)-3-acetoxy-5-hydroxy-1-(methoxycarbonyl)cyclohexane methyl (1R,3S,5R)-3-hydroxy-5-tosyloxycyclohexanecarboxylate Methyl (1R,3S,5R)-3-acetoxy-5-tosyloxy-cyclohexanecarboxylate [(1S,3R,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-bicyclo[3.1.0]hex-1-yl]-methanol

下游产品

(1R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-5-[2-[(1R,3aR,7aR)-1-((R)-5-hydroxy-1,5-dimethyl-hex-3-ynyl)-7a-methyl-octahydro-inden-(4E)-ylidene]-eth-(Z)-ylidene]-cyclohexanol