百科

1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose

1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose

CAS号：328386-10-3

英文名：1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose

分子式：C37H74O9Si4

分子量：775.32

合成路线

(2R,3S,4R,5S,6S)-3,4,5-Tris-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-propa-1,2-dienyl-tetrahydro-pyran

(2R,3S,4R,5S,6S)-3,4,5-Tris-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-propa-1,2-dienyl-tetrahydro-pyran

1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose

1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose

1-C-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)allene

1-C-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)allene

1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose

1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose

(((3S,4R,5S,6S)-6-(((trimethylsilyl)oxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl)tetrakis(oxy))tetrakis(trimethylsilane)

(((3S,4R,5S,6S)-6-(((trimethylsilyl)oxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl)tetrakis(oxy))tetrakis(trimethylsilane)

1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose

1,6-Anhydro-3-C-{(1R)-2,6-anhydro-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-manno-heptitol-1-C-yl}-2,3-dideoxy-β-D-glycero-hex-2-enopyranos-4-ulose

上游原料

1-C-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)allene (((3S,4R,5S,6S)-6-(((trimethylsilyl)oxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl)tetrakis(oxy))tetrakis(trimethylsilane) (2R,3S,4R,5S,6S)-3,4,5-Tris-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-propa-1,2-dienyl-tetrahydro-pyran

下游产品

5-(benzyl-benzyloxy-amino)-4-{hydroxy-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-methyl}-6-phenylsulfanyl-2-trimethylsilanyloxymethyl-tetrahydro-pyran-3-ol (1R,2R,3R,4R,5R)-4-(Benzyl-benzyloxy-amino)-3-{(R)-hydroxy-[(2S,3S,4S,5S,6R)-3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-methyl}-6,8-dioxa-bicyclo[3.2.1]octan-2-ol