百科

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

CAS号：329366-71-4

英文名：(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

分子式：C13H30O3Si

分子量：262.461

合成路线

{(4R,5R)-5-[(S)-1-(benzyloxy)propan-2-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}methyl-4-methylbenzenesulfonate

{(4R,5R)-5-[(S)-1-(benzyloxy)propan-2-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}methyl-4-methylbenzenesulfonate

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

(1R,2S)-3-(benzyloxy)-2-methyl-1-[(R)-oxiran-2-yl]propan-1-ol

(1R,2S)-3-(benzyloxy)-2-methyl-1-[(R)-oxiran-2-yl]propan-1-ol

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

ethyl (4R,2E)-5-(benzyloxy)-4-methylpent-2-enoate

ethyl (4R,2E)-5-(benzyloxy)-4-methylpent-2-enoate

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

(3S,4S)-4-methyl-5-(phenylmethoxy)-1-penten-3-ol

(3S,4S)-4-methyl-5-(phenylmethoxy)-1-penten-3-ol

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

(2S,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentan-1-ol

上游原料

{(4R,5R)-5-[(S)-1-(benzyloxy)propan-2-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}methyl-4-methylbenzenesulfonate ethyl (4R,2E)-5-(benzyloxy)-4-methylpent-2-enoate (3S,4S)-4-methyl-5-(phenylmethoxy)-1-penten-3-ol (1R,2S)-3-(benzyloxy)-2-methyl-1-[(R)-oxiran-2-yl]propan-1-ol

下游产品

methyl 2-{(2R,5S,6S)-6-[(2E,4Z,6S,8E,10S,11R,12R)-12-(tert-Butyldimethylsilyloxy)-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl]-5-methyltetrahydro-2H-pyran-2-yl}acetate (4S,5R,6R,Z)-ethyl 6-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dimethylhept-2-enoate methyl {(2S,3S,6R)-[[1E,3E,7E,11R,10R,9S,5R]-11-tertbutyldimethylsiloxy-10-methoxy-1,5,7,9-tetramethyldodeca-1,3,7-trienyl]-3-methyloxan-6-yl}ethanoate methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-(tert-butyldimethylsilyloxy)-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)-acetate