百科

(2R,6S,7R,8R,4E)-8-(tert-butyldimethylsiloxy)-7-methoxy-2,4,6-trimethyl-4-nonenoic acid

(2R,6S,7R,8R,4E)-8-(tert-butyldimethylsiloxy)-7-methoxy-2,4,6-trimethyl-4-nonenoic acid

CAS号：329366-75-8

英文名：(2R,6S,7R,8R,4E)-8-(tert-butyldimethylsiloxy)-7-methoxy-2,4,6-trimethyl-4-nonenoic acid

分子式：C19H38O4Si

分子量：358.588

合成路线

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentanal

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentanal

(2R,6S,7R,8R,4E)-8-(tert-butyldimethylsiloxy)-7-methoxy-2,4,6-trimethyl-4-nonenoic acid

(2R,6S,7R,8R,4E)-8-(tert-butyldimethylsiloxy)-7-methoxy-2,4,6-trimethyl-4-nonenoic acid

(3S,4S)-4-methyl-5-(phenylmethoxy)-1-penten-3-ol

(3S,4S)-4-methyl-5-(phenylmethoxy)-1-penten-3-ol

(2R,6S,7R,8R,4E)-8-(tert-butyldimethylsiloxy)-7-methoxy-2,4,6-trimethyl-4-nonenoic acid

(2R,6S,7R,8R,4E)-8-(tert-butyldimethylsiloxy)-7-methoxy-2,4,6-trimethyl-4-nonenoic acid

上游原料

(3S,4S)-4-methyl-5-(phenylmethoxy)-1-penten-3-ol (2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentanal

下游产品

methyl {(2S,3S,6R)-[[1E,3E,7E,11R,10R,9S,5R]-11-tertbutyldimethylsiloxy-10-methoxy-1,5,7,9-tetramethyldodeca-1,3,7-trienyl]-3-methyloxan-6-yl}ethanoate methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-(tert-butyldimethylsilyloxy)-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)-acetate