百科

methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-hydroxy-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

CAS号：329366-78-1

英文名：methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-hydroxy-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

分子式：C26H44O5

分子量：436.625

合成路线

177598-65-1

(2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentanal

329366-78-1

methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-hydroxy-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

96094-43-8

(1S,2R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-methyl-but-3-en-1-ol

329366-78-1

methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-hydroxy-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

329366-77-0

methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-(tert-butyldimethylsilyloxy)-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)-acetate

329366-78-1

methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-hydroxy-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

177598-64-0

tert-butyl((2R,3R,4S)-3-methoxy-4-methylhex-5-en-2-yloxy)dimethylsilane

329366-78-1

methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-hydroxy-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

176302-29-7

methyl [2R-(2α,5β,6α)]-6-formyl-5-methyltetrahydro-2H-pyran-2-acetate

329366-78-1

methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-hydroxy-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

176302-23-1

methyl [2R-(2α,5β,6α)]-6-acetyl-5-methyltetrahydro-2H-pyran-2-acetate

329366-78-1

methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-hydroxy-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate

上游原料

methyl [2R-(2α,5β,6α)]-6-formyl-5-methyltetrahydro-2H-pyran-2-acetate (2R,3R,4R)-4-(tert-butyldimethylsilyloxy)-3-methoxy-2-methylpentanal (1S,2R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-methyl-but-3-en-1-ol methyl [2R-(2α,5β,6α)]-6-acetyl-5-methyltetrahydro-2H-pyran-2-acetate methyl 2-((2R,5S,6S)-6-((2E,4E,6S,8E,10S,11R,12R)-12-(tert-butyldimethylsilyloxy)-11-methoxy-6,8,10-trimethyltrideca-2,4,8-trien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)-acetate tert-butyl((2R,3R,4S)-3-methoxy-4-methylhex-5-en-2-yloxy)dimethylsilane

下游产品

methyl 2-((2R,5S,6S)-6-((S,2E,4E)-7-((2R,3R)-3-((2R,3R,4R)-4-hydroxy-3-methoxypentan-2-yl)-2-methyloxiran-2-yl)-6-methylhepta-2,4-dien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate