(1R*,4S*,5R*,8S*)-4,5-bis(tert-butyldimethylsilyloxy)-9-oxabicyclo[6.1.0]nonane

(1R,4S,5R,8S)-4,5-bis(tert-butyldimethylsilyloxy)-9-oxabicyclo[6.1.0]nonane

CAS号：331272-97-0

英文名：(1R*,4S*,5R*,8S*)-4,5-bis(tert-butyldimethylsilyloxy)-9-oxabicyclo[6.1.0]nonane

分子式：C20H42O3Si2

分子量：386.717

合成路线

rel-(1S,2S,5Z)-cyclooct-5-en-1,2-diol

rel-(1S,2S,5Z)-cyclooct-5-en-1,2-diol

(1R*,4S*,5R*,8S*)-4,5-bis(tert-butyldimethylsilyloxy)-9-oxabicyclo[6.1.0]nonane

(1R*,4S*,5R*,8S*)-4,5-bis(tert-butyldimethylsilyloxy)-9-oxabicyclo[6.1.0]nonane

上游原料

rel-(1S,2S,5Z)-cyclooct-5-en-1,2-diol

下游产品

(3aR,4S,6aR)-3-allyl-3a,4-bis(tert-butyldimethylsilyloxy)-4,5,6,6a-tetrahydro-2-hydroxy-3aH-pentalen-1-one (3S,3aS,4S,6aS)-4-Allyl-3,3a-bis-(tert-butyl-dimethyl-silanyloxy)-6-trimethylsilanyloxy-1,2,3,3a,4,6a-hexahydro-pentalene (3aS,4S,6aR)-3a,4-bis(tert-butyldimethylsilyloxy)-4,5,6,6a-tetrahydro-3aH-pentalen-1-one