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(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

CAS号：331625-70-8

英文名：(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

分子式：C41H72O4SSi

分子量：689.158

合成路线

(S)-2-methyldodecanal

(S)-2-methyldodecanal

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(2R,3R,4S)-2,4-Dimethyl-tetradecane-1,3-diol

(2R,3R,4S)-2,4-Dimethyl-tetradecane-1,3-diol

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(2S,3R,4S)-3-Hydroxy-2,4-dimethyl-tetradecanethioic acid S-ethyl ester

(2S,3R,4S)-3-Hydroxy-2,4-dimethyl-tetradecanethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(2S,3R,4S)-3-(4-Methoxy-benzyloxy)-2,4-dimethyl-tetradecanal

(2S,3R,4S)-3-(4-Methoxy-benzyloxy)-2,4-dimethyl-tetradecanal

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(2R,3R,4S)-3-(4-Methoxy-benzyloxy)-2,4-dimethyl-tetradecan-1-ol

(2R,3R,4S)-3-(4-Methoxy-benzyloxy)-2,4-dimethyl-tetradecan-1-ol

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(E)-(4R,5R,6S)-5-(4-Methoxy-benzyloxy)-2,4,6-trimethyl-hexadec-2-enal

(E)-(4R,5R,6S)-5-(4-Methoxy-benzyloxy)-2,4,6-trimethyl-hexadec-2-enal

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(E)-(4R,5R,6S)-5-(4-Methoxy-benzyloxy)-2,4,6-trimethyl-hexadec-2-en-1-ol

(E)-(4R,5R,6S)-5-(4-Methoxy-benzyloxy)-2,4,6-trimethyl-hexadec-2-en-1-ol

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(E)-(4R,5R,6S)-5-(4-Methoxy-benzyloxy)-2,4,6-trimethyl-hexadec-2-enoic acid ethyl ester

(E)-(4R,5R,6S)-5-(4-Methoxy-benzyloxy)-2,4,6-trimethyl-hexadec-2-enoic acid ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(2E,4E)-(6R,7R,8S)-7-(4-Methoxy-benzyloxy)-2,4,6,8-tetramethyl-octadeca-2,4-dien-1-ol

(2E,4E)-(6R,7R,8S)-7-(4-Methoxy-benzyloxy)-2,4,6,8-tetramethyl-octadeca-2,4-dien-1-ol

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(2E,4E)-(6R,7R,8S)-7-(4-Methoxy-benzyloxy)-2,4,6,8-tetramethyl-octadeca-2,4-dienoic acid ethyl ester

(2E,4E)-(6R,7R,8S)-7-(4-Methoxy-benzyloxy)-2,4,6,8-tetramethyl-octadeca-2,4-dienoic acid ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

(4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienethioic acid S-ethyl ester

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上游原料

(2R,3R,4S)-2,4-Dimethyl-tetradecane-1,3-diol (2E,4E)-(6R,7R,8S)-7-(4-Methoxy-benzyloxy)-2,4,6,8-tetramethyl-octadeca-2,4-dienal (E)-(4R,5R,6S)-5-(4-Methoxy-benzyloxy)-2,4,6-trimethyl-hexadec-2-en-1-ol (S)-2-methyldodecanal (E)-(4R,5R,6S)-5-(4-Methoxy-benzyloxy)-2,4,6-trimethyl-hexadec-2-enoic acid ethyl ester (2E,4E)-(6R,7R,8S)-7-(4-Methoxy-benzyloxy)-2,4,6,8-tetramethyl-octadeca-2,4-dien-1-ol (2S,3R,4S)-3-Hydroxy-2,4-dimethyl-tetradecanethioic acid S-ethyl ester (2S,3R,4S)-3-(4-Methoxy-benzyloxy)-2,4-dimethyl-tetradecanal (2R,3R,4S)-3-(4-Methoxy-benzyloxy)-2,4-dimethyl-tetradecan-1-ol (E)-(4R,5R,6S)-5-(4-Methoxy-benzyloxy)-2,4,6-trimethyl-hexadec-2-enal (2E,4E)-(6R,7R,8S)-7-(4-Methoxy-benzyloxy)-2,4,6,8-tetramethyl-octadeca-2,4-dienoic acid ethyl ester

下游产品

(2E,6E,8E)-(4R,5S,10R,11R,12S)-5-Hydroxy-11-(4-methoxy-benzyloxy)-2,4,6,8,10,12-hexamethyl-docosa-2,6,8-trienoic acid ethyl ester (2E,6E,8E)-(4R,10R,11R,12S)-11-(4-Methoxy-benzyloxy)-2,4,6,8,10,12-hexamethyl-5-oxo-docosa-2,6,8-trienoic acid ethyl ester (2E,6E,8E)-(4R,5S,10R,11R,12S)-11-(4-Methoxy-benzyloxy)-2,4,6,8,10,12-hexamethyl-5-triethylsilanyloxy-docosa-2,6,8-trienoic acid ethyl ester (4E,6E)-(2S,3S,8R,9R,10S)-9-(4-Methoxy-benzyloxy)-2,4,6,8,10-pentamethyl-3-triethylsilanyloxy-icosa-4,6-dienal