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(4R,5R,6S,E)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-en-1-ol

(4R,5R,6S,E)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-en-1-ol

CAS号：331814-93-8

英文名：(4R,5R,6S,E)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-en-1-ol

分子式：C17H36O2Si

分子量：300.552

合成路线

(2S,3R,4S)-3-[(tert-butyl)dimethylsilyloxy]-2,4-dimethylhexanal

(2S,3R,4S)-3-[(tert-butyl)dimethylsilyloxy]-2,4-dimethylhexanal

(4R,5R,6S,E)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-en-1-ol

(4R,5R,6S,E)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-en-1-ol

(E)-ethyl 3-((2R,3R)-3-((S)-sec-butyl)-2-methyloxiran-2-yl)-2-methylacrylate

(E)-ethyl 3-((2R,3R)-3-((S)-sec-butyl)-2-methyloxiran-2-yl)-2-methylacrylate

(4R,5R,6S,E)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-en-1-ol

(4R,5R,6S,E)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-en-1-ol

(4R,5R,6S,E)-ethyl 5-hydroxy-2,4,6-trimethyloct-2-enoate

(4R,5R,6S,E)-ethyl 5-hydroxy-2,4,6-trimethyloct-2-enoate

(4R,5R,6S,E)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-en-1-ol

(4R,5R,6S,E)-5-(tert-butyldimethylsilyloxy)-2,4,6-trimethyloct-2-en-1-ol

上游原料

(4R,5R,6S,E)-ethyl 5-hydroxy-2,4,6-trimethyloct-2-enoate (2S,3R,4S)-3-[(tert-butyl)dimethylsilyloxy]-2,4-dimethylhexanal (E)-ethyl 3-((2R,3R)-3-((S)-sec-butyl)-2-methyloxiran-2-yl)-2-methylacrylate

下游产品

(E)-ethyl 3-((2R,3R)-3-((2R,3R,4S)-3-(tert-butyldimethylsilyloxy)-4-methylhexan-2-yl)-2-methyloxiran-2-yl)-2-methylacrylate (4R,5S,6S,7R,8S,E)-ethyl 5,7-dihydroxy-2,4,6,8-tetramethyldec-2-enoate (R)-6-((1E,3Z,7E,9E)-(5R,11R,12R,13S)-3-Ethyl-12-hydroxy-5,9,11,13-tetramethyl-pentadeca-1,3,7,9-tetraenyl)-5,6-dihydro-pyran-2-one (R)-6-[(1E,3Z,7E,9E)-(5R,11R,12R,13S)-12-(tert-Butyl-dimethyl-silanyloxy)-3-ethyl-5,9,11,13-tetramethyl-pentadeca-1,3,7,9-tetraenyl]-5,6-dihydro-pyran-2-one (4R,5S,6R,7R,8S,E)-7-((tert-butyldimethylsilyl)oxy)-5-hydroxy-2,4,6,8-tetramethyldec-2-enal (R,E)-ethyl 4-((4S,5S,6R)-6-((S)-sec-butyl)-2,2,5-trimethyl-1,3-dioxan-4-yl)-2-methylpent-2-enoate