百科

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

CAS号：332057-86-0

英文名：(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

分子式：C48H55NO10S

分子量：838.016

合成路线

methyl α-D-mannopyranoside 2-benzyl ether

methyl α-D-mannopyranoside 2-benzyl ether

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

(2R,3S,4S,5R,6S)-5-Benzyloxy-6-methoxy-2-trityloxymethyl-tetrahydro-pyran-3,4-diol

(2R,3S,4S,5R,6S)-5-Benzyloxy-6-methoxy-2-trityloxymethyl-tetrahydro-pyran-3,4-diol

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

Acetic acid (2R,3R,4S,5R,6S)-4-acetoxy-5-benzyloxy-6-methoxy-2-trityloxymethyl-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3R,4S,5R,6S)-4-acetoxy-5-benzyloxy-6-methoxy-2-trityloxymethyl-tetrahydro-pyran-3-yl ester

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-1-trityloxymethyl-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene

上游原料

methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside methyl α-D-mannopyranoside 2-benzyl ether Acetic acid (2R,3R,4S,5R,6S)-4-acetoxy-5-benzyloxy-6-methoxy-2-trityloxymethyl-tetrahydro-pyran-3-yl ester (2R,3S,4S,5R,6S)-5-Benzyloxy-6-methoxy-2-trityloxymethyl-tetrahydro-pyran-3,4-diol

下游产品

[(1R,3S,4R,4aS,17aR)-4-Benzyloxy-3-methoxy-11-(toluene-4-sulfonyl)-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecen-1-yl]-methanol (1R,3S,4R,4aS,17aR)-4-Benzyloxy-1-butoxymethyl-3-methoxy-11-(toluene-4-sulfonyl)-dodecahydro-2,5,8,14,17-pentaoxa-11-aza-benzocyclopentadecene