百科

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

CAS号：333788-73-1

英文名：(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

分子式：C26H36O5

分子量：428.561

合成路线

333788-82-2

(Z)-(2R,3R,8R,9S)-9-Benzyloxy-2,8-bis-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-undec-5-en-3-ol

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

333788-83-3

Methanesulfonic acid (Z)-(1R,6R,7S)-7-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-1-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxy)-ethyl]-non-3-enyl ester

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

333788-77-5

(2R,3R)-2-Benzyloxy-3-(1-methoxy-1-methyl-ethoxy)-succinic acid diethyl ester

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

333788-80-0

Methanesulfonic acid (1S,2S)-2-benzyloxy-1-(tert-butyl-dimethyl-silanyloxymethyl)-butyl ester

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

104211-01-0

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

99838-63-8

(R)-2-((S)-1-(benzyloxy)propyl)oxirane

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

108740-35-8

(2S,3S)-3-Benzyloxy-pentane-1,2-diol

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

334793-69-0

(S)-4-((S)-1-Benzyloxy-propyl)-2,2-dimethyl-[1,3]dioxolane

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

333788-81-1

(4R,5S)-5-Benzyloxy-hept-1-yn-4-ol

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

333788-78-6

(2S,3S)-2-Benzyloxy-3-(1-methoxy-1-methyl-ethoxy)-butane-1,4-diol

333788-73-1

(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-1-ol

上游原料

(S)-4-((S)-1-Benzyloxy-propyl)-2,2-dimethyl-[1,3]dioxolane (Z)-(3S,4R)-3-Benzyloxy-8-[(2S,3R)-3-(4-methoxy-benzyloxymethyl)-oxiranyl]-oct-6-en-4-ol (2S,3S)-3-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-pentan-2-ol (R)-2-((S)-1-(benzyloxy)propyl)oxirane (R)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-2-(4-methoxy-benzyloxy)-ethanol (2S,3S)-3-Benzyloxy-pentane-1,2-diol (2R,3R)-2-Benzyloxy-3-(1-methoxy-1-methyl-ethoxy)-succinic acid diethyl ester [(R)-1-((S)-1-Benzyloxy-propyl)-but-3-ynyloxy]-tert-butyl-dimethyl-silane (2S,3S)-2-Benzyloxy-3-(1-methoxy-1-methyl-ethoxy)-butane-1,4-diol Methanesulfonic acid (1S,2S)-2-benzyloxy-1-(tert-butyl-dimethyl-silanyloxymethyl)-butyl ester (4R,5S)-5-Benzyloxy-hept-1-yn-4-ol Methanesulfonic acid (R)-1-[(2R,7R)-7-((S)-1-benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-2-hydroxy-ethyl ester Methanesulfonic acid (R)-1-[(2R,7R)-7-((S)-1-benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-2-(4-methoxy-benzyloxy)-ethyl ester (2R,3R,8R,9S)-9-Benzyloxy-2,8-bis-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-undec-5-yn-3-ol (Z)-(2R,3R,8R,9S)-9-Benzyloxy-2,8-bis-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-undec-5-en-3-ol Methanesulfonic acid (Z)-(1R,6R,7S)-7-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-1-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxy)-ethyl]-non-3-enyl ester

下游产品

(S)-1-[(2R,7R)-7-((Z)-(R)-1-Chloro-hex-3-en-5-ynyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-propan-1-ol (Z)-(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-en-1-ol Acetic acid (Z)-(S)-1-[(2R,7R)-7-((S)-1-benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-(tetrahydro-pyran-2-yloxy)-pent-3-enyl ester (Z)-(S)-1-[(2R,7R)-7-((S)-1-Benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-hex-3-en-5-yn-1-ol (2R,7R)-2-((S)-1-Benzyloxy-propyl)-7-((Z)-(R)-1-chloro-hex-3-en-5-ynyl)-2,3,6,7-tetrahydro-oxepine Acetic acid (Z)-(S)-1-[(2R,7R)-7-((S)-1-benzyloxy-propyl)-2,3,6,7-tetrahydro-oxepin-2-yl]-5-hydroxy-pent-3-enyl ester