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(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

CAS号：334972-61-1

英文名：(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

分子式：C27H42O4SSi

分子量：490.77

合成路线

(S)-5-(tert-Butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)pentanal

(S)-5-(tert-Butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)pentanal

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(S)-tert-butyl((2-((4-methoxybenzyl)oxy)hex-5-en-1-yl)oxy)dimethylsilane

(S)-tert-butyl((2-((4-methoxybenzyl)oxy)hex-5-en-1-yl)oxy)dimethylsilane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2S,5R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-5-(1-methylethenyl)cyclopentanol

(1S,2S,5R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-5-(1-methylethenyl)cyclopentanol

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(R)-2-[(1'S,2'R,5'R)-1'-(tert-Butyldimethylsilyloxy)-5'-(1-methylethenyl)-2'-cyclopentyl]tetrahydropyran-5-one

(R)-2-[(1'S,2'R,5'R)-1'-(tert-Butyldimethylsilyloxy)-5'-(1-methylethenyl)-2'-cyclopentyl]tetrahydropyran-5-one

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-6-methylhept-5-enal

(R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-6-methylhept-5-enal

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

Ethyl (R)-2-[(2'R,5'S)-5'-(4-methoxybenzyloxy)tetrahydropyran-2'-yl]-6-methylhept-5-enoate

Ethyl (R)-2-[(2'R,5'S)-5'-(4-methoxybenzyloxy)tetrahydropyran-2'-yl]-6-methylhept-5-enoate

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

(1S,2R,5R)-2-[(2'R,5'Z)-5'-(2''-Phenylsulfonylethylidene)-tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane

上游原料

(R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-6-methylhept-5-enal Ethyl (R)-2-[(2'R,5'S)-5'-(4-methoxybenzyloxy)tetrahydropyran-2'-yl]-6-methylhept-5-enoate (1S,2R,5R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane (S)-tert-butyl((2-((4-methoxybenzyl)oxy)hex-5-en-1-yl)oxy)dimethylsilane (R)-2-[(1'S,2'R,5'R)-1'-(tert-Butyldimethylsilyloxy)-5'-(1-methylethenyl)-2'-cyclopentyl]tetrahydropyran-5-one (S)-5-(tert-Butyldimethylsilyloxy)-4-(4-methoxybenzyloxy)pentanal (1S,2S,5R)-2-[(2'R,5'S)-5'-(4-Methoxybenzyloxy)tetrahydropyran-2'-yl]-5-(1-methylethenyl)cyclopentanol

下游产品

(1S,1'S,2R,2'R,5R,5'R)-2,2'-{5,5'-[(R,S)-2-Phenylsulfonylbutane-1,4-diylidene]bis[(2R,5Z)-tetrahydropyran-2-yl]}bis[1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane] (1S,1'S,2R,2'R,5R,5'R)-2,2'-{5,5'-[Butane-1,4-diylidene]bis[(2R,5Z)-tetrahydropyran-2-yl]}bis[1-(tert-butyldimethylsilyloxy)-5-(1-methylethenyl)cyclopentane]