百科

(4S,6R)-4-tert-butyldimethylsilyloxy-6-hydroxymethyl-2-cyclohexenone

(4S,6R)-4-tert-butyldimethylsilyloxy-6-hydroxymethyl-2-cyclohexenone

CAS号：338460-84-7

英文名：(4S,6R)-4-tert-butyldimethylsilyloxy-6-hydroxymethyl-2-cyclohexenone

分子式：C13H24O3Si

分子量：256.413

合成路线

dimethyl (1S,2R,5S)-5-tert-butyldimethylsilyloxy-2-hydroxy-3-cyclohexene-1,2-dicarboxylate

dimethyl (1S,2R,5S)-5-tert-butyldimethylsilyloxy-2-hydroxy-3-cyclohexene-1,2-dicarboxylate

(4S,6R)-4-tert-butyldimethylsilyloxy-6-hydroxymethyl-2-cyclohexenone

(4S,6R)-4-tert-butyldimethylsilyloxy-6-hydroxymethyl-2-cyclohexenone

上游原料

dimethyl (1S,2R,5S)-5-tert-butyldimethylsilyloxy-2-hydroxy-3-cyclohexene-1,2-dicarboxylate

下游产品

5a-carba-α-D-mannopyranose (3S,4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-4-trimethylsilanyloxymethyl-cyclohexene tert-butyldimethylsilyl 4,6-di-O-benzyl-5a-carba-α-D-mannopyranoside (1S,2S,3R,4R,5R)-1-tert-butyldimethylsilyloxy-2,3-epoxy-4-trimethylsilyloxy-5-trimethylsilyloxymethylcyclohexane tert-butyldimethylsilyl 2,3,4,6-tetra-O-benzyl-5a-carba-α-D-mannopyranoside (1R,2R,3S,5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-2-trimethylsilanyloxy-7-oxa-bicyclo[4.1.0]heptane-3-carbaldehyde