百科

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

CAS号：342901-10-4

英文名：(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

分子式：C14H28O3Si

分子量：272.456

合成路线

ethyl (2E,4R,5R)-4-hydroxy-5-[(methylsulfonyl)oxy]-4-methylhex-2-enoate

ethyl (2E,4R,5R)-4-hydroxy-5-[(methylsulfonyl)oxy]-4-methylhex-2-enoate

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

ethyl 2-((2S,4R,5S,6S)-5,6-dimethyl-2-phenyl-1,3-dioxan-4-yl)acetate

ethyl 2-((2S,4R,5S,6S)-5,6-dimethyl-2-phenyl-1,3-dioxan-4-yl)acetate

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

ethyl (2E,4R,5S)-5-hydroxy-4-methylhex-2-enoate

ethyl (2E,4R,5S)-5-hydroxy-4-methylhex-2-enoate

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

ethyl (E)-3-[(2S,3S)-2,3-dimethyloxiran-2-yl]prop-2-enoate

ethyl (E)-3-[(2S,3S)-2,3-dimethyloxiran-2-yl]prop-2-enoate

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(2E,4E)-4-甲基-2,4-己二烯酸乙酯

(2E,4E)-4-甲基-2,4-己二烯酸乙酯

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

ethyl (2E,4R,5R)-4,5-dihydroxy-4-methylhex-2-enoate

ethyl (2E,4R,5R)-4,5-dihydroxy-4-methylhex-2-enoate

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(4S,5S,6S)-3,4,5,6-tetrahydro-4-hydroxy-5,6-dimethyl-2H-pyran-2-one

(4S,5S,6S)-3,4,5,6-tetrahydro-4-hydroxy-5,6-dimethyl-2H-pyran-2-one

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

(3R,4R,5S,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-one

上游原料

ethyl (2E,4R,5R)-4,5-dihydroxy-4-methylhex-2-enoate (4S,5S,6S)-3,4,5,6-tetrahydro-4-hydroxy-5,6-dimethyl-2H-pyran-2-one ethyl (2E,4R,5R)-4-hydroxy-5-[(methylsulfonyl)oxy]-4-methylhex-2-enoate ethyl (E)-3-[(2S,3S)-2,3-dimethyloxiran-2-yl]prop-2-enoate ethyl 2-((2S,4R,5S,6S)-5,6-dimethyl-2-phenyl-1,3-dioxan-4-yl)acetate ethyl (2E,4R,5S)-5-hydroxy-4-methylhex-2-enoate (2E,4E)-4-甲基-2,4-己二烯酸乙酯

下游产品

(3R,4R,5R,6S)-3,4,5,6-tetrahydro-2-(2,2-dimethylhydrazino)-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran (3R,4R,5R,6S)-3,4,5,6-tetrahydro-3,5,6-trimethyl-4-(triethylsilyloxy)-2H-pyran-2-ol (2R,3S,4R,5R)-2,4-dimethyl-3-(triethylsilyloxy)-5-(triisopropylsilyloxy)hexanal dimethylhydrazone