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(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl 5-hexenoate

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl 5-hexenoate

CAS号：343764-44-3

英文名：(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl 5-hexenoate

分子式：C17H28O4

分子量：296.402

合成路线

Methyl 4,5-epoxy-2,3-O-isopropylidene-L-lyxonate

Methyl 4,5-epoxy-2,3-O-isopropylidene-L-lyxonate

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl 5-hexenoate

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl 5-hexenoate

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl benzoate

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl benzoate

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl 5-hexenoate

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl 5-hexenoate

3,4-anhydro-5-O-benzyl-1,2-dideoxy-D-threo-pent-1-enitol

3,4-anhydro-5-O-benzyl-1,2-dideoxy-D-threo-pent-1-enitol

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl 5-hexenoate

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl 5-hexenoate

上游原料

3,4-anhydro-5-O-benzyl-1,2-dideoxy-D-threo-pent-1-enitol (1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl benzoate Methyl 4,5-epoxy-2,3-O-isopropylidene-L-lyxonate

下游产品

(+)-lethaloxin (2E,4E)-Hexa-2,4-dienoic acid (E)-(3aR,4R,7S,11aS)-2,2-dimethyl-6-oxo-4-propyl-3a,6,7,8,9,11a-hexahydro-4H-1,3,5-trioxa-cyclopentacyclodecen-7-yl ester