百科

(E)-(3aR,4R,11aS)-2,2-Dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,11aS)-2,2-Dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

CAS号：343764-45-4

英文名：(E)-(3aR,4R,11aS)-2,2-Dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

分子式：C15H24O4

分子量：268.349

合成路线

Methyl 4,5-epoxy-2,3-O-isopropylidene-L-lyxonate

Methyl 4,5-epoxy-2,3-O-isopropylidene-L-lyxonate

(E)-(3aR,4R,11aS)-2,2-Dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,11aS)-2,2-Dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl benzoate

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl benzoate

(E)-(3aR,4R,11aS)-2,2-Dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

(E)-(3aR,4R,11aS)-2,2-Dimethyl-4-propyl-3a,4,7,8,9,11a-hexahydro-1,3,5-trioxa-cyclopentacyclodecen-6-one

上游原料

(1R)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]butyl benzoate Methyl 4,5-epoxy-2,3-O-isopropylidene-L-lyxonate

下游产品

(+)-lethaloxin (2E,4E)-Hexa-2,4-dienoic acid (E)-(3aR,4R,7S,11aS)-2,2-dimethyl-6-oxo-4-propyl-3a,6,7,8,9,11a-hexahydro-4H-1,3,5-trioxa-cyclopentacyclodecen-7-yl ester