百科

2-((2S,3S,4R,4aR,5aR,9R,10aS,11aR)-2-Allyl-3,4-bis-benzyloxy-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-9-yl)-ethanol

2-((2S,3S,4R,4aR,5aR,9R,10aS,11aR)-2-Allyl-3,4-bis-benzyloxy-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-9-yl)-ethanol

CAS号：344315-31-7

英文名：2-((2S,3S,4R,4aR,5aR,9R,10aS,11aR)-2-Allyl-3,4-bis-benzyloxy-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-9-yl)-ethanol

分子式：C37H52O6Si

分子量：620.891

合成路线

Acetic acid 2-((2R,3R,4S,5S,6S)-6-allyl-4,5-bis-benzyloxy-3-hydroxy-tetrahydro-pyran-2-yl)-1-[2-(2-hydroxy-ethyl)-[1,3]dithian-2-yl]-ethyl ester

Acetic acid 2-((2R,3R,4S,5S,6S)-6-allyl-4,5-bis-benzyloxy-3-hydroxy-tetrahydro-pyran-2-yl)-1-[2-(2-hydroxy-ethyl)-[1,3]dithian-2-yl]-ethyl ester

2-((2S,3S,4R,4aR,5aR,9R,10aS,11aR)-2-Allyl-3,4-bis-benzyloxy-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-9-yl)-ethanol

2-((2S,3S,4R,4aR,5aR,9R,10aS,11aR)-2-Allyl-3,4-bis-benzyloxy-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-9-yl)-ethanol

methyl 2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-glucopyranoside

methyl 2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-glucopyranoside

2-((2S,3S,4R,4aR,5aR,9R,10aS,11aR)-2-Allyl-3,4-bis-benzyloxy-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-9-yl)-ethanol

2-((2S,3S,4R,4aR,5aR,9R,10aS,11aR)-2-Allyl-3,4-bis-benzyloxy-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-9-yl)-ethanol

methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside

methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside

2-((2S,3S,4R,4aR,5aR,9R,10aS,11aR)-2-Allyl-3,4-bis-benzyloxy-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-9-yl)-ethanol

2-((2S,3S,4R,4aR,5aR,9R,10aS,11aR)-2-Allyl-3,4-bis-benzyloxy-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-9-yl)-ethanol

上游原料

Acetic acid 2-((2R,3R,4S,5S,6S)-6-allyl-4,5-bis-benzyloxy-3-hydroxy-tetrahydro-pyran-2-yl)-1-[2-(2-hydroxy-ethyl)-[1,3]dithian-2-yl]-ethyl ester methyl 2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-glucopyranoside methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside

下游产品

methyl 2-((1aS,2R,3aS,4aR,6S,7S,8R,8aR,9aR,10aS)-7,8-bis(benzyloxy)-6-(2-oxopropyl)-10a-(triethylsilyl)dodecahydrooxireno[2,3-e]pyrano[2',3':5,6]pyrano[3,2-b]oxepin-2-yl)acetate