百科

(2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4-Bis-benzyloxy-2-(2-methyl-[1,3]dithian-2-ylmethyl)-9-prop-2-ynyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol

CAS号：344315-43-1

英文名：(2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4-Bis-benzyloxy-2-(2-methyl-[1,3]dithian-2-ylmethyl)-9-prop-2-ynyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol

分子式：C35H42O6S2

分子量：622.834

合成路线

440339-72-0

Acetic acid 2-((2R,3R,4S,5S,6S)-6-allyl-4,5-bis-benzyloxy-3-hydroxy-tetrahydro-pyran-2-yl)-1-[2-(2-hydroxy-ethyl)-[1,3]dithian-2-yl]-ethyl ester

344315-43-1

(2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4-Bis-benzyloxy-2-(2-methyl-[1,3]dithian-2-ylmethyl)-9-prop-2-ynyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol

76491-08-2

methyl 2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-glucopyranoside

344315-43-1

(2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4-Bis-benzyloxy-2-(2-methyl-[1,3]dithian-2-ylmethyl)-9-prop-2-ynyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol

87326-88-3

methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside

344315-43-1

(2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4-Bis-benzyloxy-2-(2-methyl-[1,3]dithian-2-ylmethyl)-9-prop-2-ynyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol

440339-68-4

2,2-Dimethyl-propionic acid (2S,3S,4S,5R)-4,5-bis-benzyloxy-2-iodomethyl-6-oxo-tetrahydro-pyran-3-yl ester

344315-43-1

(2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4-Bis-benzyloxy-2-(2-methyl-[1,3]dithian-2-ylmethyl)-9-prop-2-ynyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol

440339-69-5

2,2-Dimethyl-propionic acid (2S,3S,4R,5S,6S)-6-allyl-4,5-bis-benzyloxy-2-iodomethyl-tetrahydro-pyran-3-yl ester

344315-43-1

(2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4-Bis-benzyloxy-2-(2-methyl-[1,3]dithian-2-ylmethyl)-9-prop-2-ynyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol

440339-73-1

2,2-Dimethyl-propionic acid 2-{2-[1-acetoxy-2-((2R,3R,4S,5S,6S)-6-allyl-4,5-bis-benzyloxy-3-hydroxy-tetrahydro-pyran-2-yl)-ethyl]-[1,3]dithian-2-yl}-ethyl ester

344315-43-1

(2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4-Bis-benzyloxy-2-(2-methyl-[1,3]dithian-2-ylmethyl)-9-prop-2-ynyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol

440339-80-0

1-[(2S,3S,4R,4aR,5aR,9R,10aS,11aR)-3,4-Bis-benzyloxy-9-(2-hydroxy-ethyl)-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-2-yl]-propan-2-one

344315-43-1

(2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4-Bis-benzyloxy-2-(2-methyl-[1,3]dithian-2-ylmethyl)-9-prop-2-ynyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-8-ol

上游原料

2,2-Dimethyl-propionic acid 2-{2-[1-acetoxy-2-((2R,3R,4S,5S,6S)-6-allyl-4,5-bis-benzyloxy-3-hydroxy-tetrahydro-pyran-2-yl)-ethyl]-[1,3]dithian-2-yl}-ethyl ester Acetic acid 2-((2R,3R,4S,5S,6S)-6-allyl-4,5-bis-benzyloxy-3-hydroxy-tetrahydro-pyran-2-yl)-1-[2-(2-hydroxy-ethyl)-[1,3]dithian-2-yl]-ethyl ester methyl 2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-glucopyranoside 2,2-Dimethyl-propionic acid (2S,3S,4S,5R)-4,5-bis-benzyloxy-2-iodomethyl-6-oxo-tetrahydro-pyran-3-yl ester methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside 1-[(2S,3S,4R,4aR,5aR,9R,10aS,11aR)-3,4-Bis-benzyloxy-9-(2-hydroxy-ethyl)-7-triethylsilanyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-2-yl]-propan-2-one 2,2-Dimethyl-propionic acid (2S,3S,4R,5S,6S)-6-allyl-4,5-bis-benzyloxy-2-iodomethyl-tetrahydro-pyran-3-yl ester

下游产品

(2S,3S,4R,4aR,5aR,7aS,9R,10R,12aR,13aS,14aR)-3,4-bis(benzyloxy)-2-((2-methyl-1,3-dithian-2-yl)methyl)-9-((Z)-pent-2-en-4-yn-1-yl)-2,3,4,4a,5a,7a,9,10,12a,13a,14,14a-dodecahydrooxepino[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepin-10-ol 1-((2S,3S,4R,4aR,5aR,7aS,9R,12aR,13aS,14aR)-3,4-bis(benzyloxy)-9-(2-hydroxyethyl)-11-(triethylsilyl)-2,3,4,4a,5a,7a,9,12,12a,13a,14,14a-dodecahydrooxepino[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepin-2-yl)propan-2-one