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(3R,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

(3R,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

CAS号：344796-32-3

英文名：(3R,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

分子式：C24H42O4Si

分子量：422.673

合成路线

B-crotyldiisopinocampheylborane

B-crotyldiisopinocampheylborane

(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

(3S,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

(3S,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

(3R,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

(3R,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

B-crotyldiisopinocampheylborane

B-crotyldiisopinocampheylborane

(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal

(1S,2S,3S,5R)-(+)-异松蒎醇

(1S,2S,3S,5R)-(+)-异松蒎醇

(3S,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

(3S,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

(3R,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

(3R,4R,5S,6S,7S)-6-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-3,5-dimethyl-oct-1-en-4-ol

上游原料

(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-2-methyl-pentanal B-crotyldiisopinocampheylborane

下游产品

N-[(1R,2S,3S,4R,5R)-2-(tert-Butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-4-triethylsilanyloxy-hept-6-enyl]-acetamide (2S,3S,4S,5R,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-5-triethylsilanyloxy-oct-7-en-2-ol (3R,4R,5S,6S,7R)-7-Azido-6-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-4-triethylsilanyloxy-oct-1-ene N-[(1R,2S,3S,4S,5S)-2-(tert-Butyl-dimethyl-silanyloxy)-1,3,5-trimethyl-6-oxo-4-triethylsilanyloxy-hexyl]-acetamide