百科

(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

CAS号：352422-88-9

英文名：(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

分子式：C17H20O5

分子量：304.338

合成路线

(5R)-3-O-Benzyl-6,7-dideoxy-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribo-hept-6-enofuranose

(5R)-3-O-Benzyl-6,7-dideoxy-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribo-hept-6-enofuranose

(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

(5S)-3-O-Benzyl-6,7-dideoxy-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribo-hept-6-enofuranose

(5S)-3-O-Benzyl-6,7-dideoxy-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribo-hept-6-enofuranose

(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

(1R,2R,6R,8R,9S)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

(1R,2R,6R,8R,9S)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

(1R,2R,6R,8R,9R)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

上游原料

(5S)-3-O-Benzyl-6,7-dideoxy-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribo-hept-6-enofuranose (5R)-3-O-Benzyl-6,7-dideoxy-1,2-di-O-isopropylidene-3-C-vinyl-α-D-ribo-hept-6-enofuranose (1R,2R,6R,8R,9S)-1-Benzyloxy-9-hydroxy-4,4-dimethyl-3,5,7-trioxatricyclo[6.3.0.02.6]undec-10-ene

下游产品

(1R,3R,5R,8R)-5,8-dihydroxy-3-(thymin-1-yl)-2-oxabicyclo[3.3.0]octane (1R,3R,4R,5R,8R)-5,8-Bis(benzyloxy)-4-pentafluorophenoxythiocarbonyloxy-3-(thymin-1-yl)-2-oxabicyclo[3.3.0]oct-6-ene (1R,3R,4R,5R,8R)-4-Acetoxy-5,8-bis(benzyloxy)-3-(thymin-1-yl)-2-oxabicyclo[3.3.0]oct-6-ene (1R,3R,5R,8R)-5,8-Bis(benzyloxy)-3-(thymin-1-yl)-2-oxabicyclo[3.3.0]octane