Acetic acid (3aS,10S,11aS)-10-(tert-butyl-dimethyl-silanyloxymethyl)-11-hydroxy-9-methoxy-2,2,7-trimethyl-3a,10,11,11a-tetrahydro-4H-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-5-yl ester

Acetic acid (3aS,10S,11aS)-10-(tert-butyl-dimethyl-silanyloxymethyl)-11-hydroxy-9-methoxy-2,2,7-trimethyl-3a,10,11,11a-tetrahydro-4H-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-5-yl ester

CAS号：359818-71-6

英文名：Acetic acid (3aS,10S,11aS)-10-(tert-butyl-dimethyl-silanyloxymethyl)-11-hydroxy-9-methoxy-2,2,7-trimethyl-3a,10,11,11a-tetrahydro-4H-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-5-yl ester

分子式：C25H41NO7Si

分子量：495.681

合成路线

(R)-1-((3aS,10S,11aS)-11-Hydroxy-9-methoxy-2,2,7-trimethyl-3a,4,5,10,11,11a-hexahydro-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-10-yl)-ethane-1,2-diol

(R)-1-((3aS,10S,11aS)-11-Hydroxy-9-methoxy-2,2,7-trimethyl-3a,4,5,10,11,11a-hexahydro-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-10-yl)-ethane-1,2-diol

Acetic acid (3aS,10S,11aS)-10-(tert-butyl-dimethyl-silanyloxymethyl)-11-hydroxy-9-methoxy-2,2,7-trimethyl-3a,10,11,11a-tetrahydro-4H-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-5-yl ester

Acetic acid (3aS,10S,11aS)-10-(tert-butyl-dimethyl-silanyloxymethyl)-11-hydroxy-9-methoxy-2,2,7-trimethyl-3a,10,11,11a-tetrahydro-4H-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-5-yl ester

(3aS,10S,11aS)-10-Hydroxymethyl-9-methoxy-2,2,7-trimethyl-3a,4,5,10,11,11a-hexahydro-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-11-ol

(3aS,10S,11aS)-10-Hydroxymethyl-9-methoxy-2,2,7-trimethyl-3a,4,5,10,11,11a-hexahydro-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-11-ol

Acetic acid (3aS,10S,11aS)-10-(tert-butyl-dimethyl-silanyloxymethyl)-11-hydroxy-9-methoxy-2,2,7-trimethyl-3a,10,11,11a-tetrahydro-4H-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-5-yl ester

Acetic acid (3aS,10S,11aS)-10-(tert-butyl-dimethyl-silanyloxymethyl)-11-hydroxy-9-methoxy-2,2,7-trimethyl-3a,10,11,11a-tetrahydro-4H-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-5-yl ester

2,2,2-trifluoro-1-((3R,3aR,9aS,12aS)-3-(hydroxymethyl)-4-methoxy-6,11,11-trimethyl-3,3a,9a,12a-tetrahydrobenzo[b][1,3]dioxolo[4,5-f]isoxazolo[4,3-d]azocin-8(9H)-yl)ethan-1-one

2,2,2-trifluoro-1-((3R,3aR,9aS,12aS)-3-(hydroxymethyl)-4-methoxy-6,11,11-trimethyl-3,3a,9a,12a-tetrahydrobenzo[b][1,3]dioxolo[4,5-f]isoxazolo[4,3-d]azocin-8(9H)-yl)ethan-1-one

Acetic acid (3aS,10S,11aS)-10-(tert-butyl-dimethyl-silanyloxymethyl)-11-hydroxy-9-methoxy-2,2,7-trimethyl-3a,10,11,11a-tetrahydro-4H-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-5-yl ester

Acetic acid (3aS,10S,11aS)-10-(tert-butyl-dimethyl-silanyloxymethyl)-11-hydroxy-9-methoxy-2,2,7-trimethyl-3a,10,11,11a-tetrahydro-4H-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-5-yl ester

上游原料

2,2,2-trifluoro-1-((3R,3aR,9aS,12aS)-3-(hydroxymethyl)-4-methoxy-6,11,11-trimethyl-3,3a,9a,12a-tetrahydrobenzo[b][1,3]dioxolo[4,5-f]isoxazolo[4,3-d]azocin-8(9H)-yl)ethan-1-one (3aS,10S,11aS)-10-Hydroxymethyl-9-methoxy-2,2,7-trimethyl-3a,4,5,10,11,11a-hexahydro-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-11-ol (R)-1-((3aS,10S,11aS)-11-Hydroxy-9-methoxy-2,2,7-trimethyl-3a,4,5,10,11,11a-hexahydro-1,3-dioxa-5-aza-benzo[a]cyclopenta[e]cycloocten-10-yl)-ethane-1,2-diol

下游产品

(3aS,10S,11aR)-10-(hydroxymethyl)-9-methoxy-2,2,7-trimethyl-3a,11a-dihydro-4H-5,11-epoxybenzo[b][1,3]dioxolo[4,5-f]azocin-11(10H)-ol