百科

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

CAS号：363140-03-8

英文名：2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

分子式：C23H32O5

分子量：388.497

合成路线

5,8a-dimethyl-3,4,8,8a-tetrahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-6(7H)-one

5,8a-dimethyl-3,4,8,8a-tetrahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-6(7H)-one

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

(4aS,8aR)-6-Hydroxymethyl-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-2H-naphthalen-1-one

(4aS,8aR)-6-Hydroxymethyl-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-2H-naphthalen-1-one

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

(4aS,8aR)-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbaldehyde

(4aS,8aR)-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbaldehyde

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

(4aS,8aR)-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbonitrile

(4aS,8aR)-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbonitrile

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

(4aS,5R,6S,8aR)-5,6,8a-trimethyl-5-vinyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]

(4aS,5R,6S,8aR)-5,6,8a-trimethyl-5-vinyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

cis-decaline

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

((1S,4aR,8aS)-1,4a-Dimethyl-2-methylene-5-oxo-decahydro-naphthalen-1-yl)-acetic acid ethyl ester

((1S,4aR,8aS)-1,4a-Dimethyl-2-methylene-5-oxo-decahydro-naphthalen-1-yl)-acetic acid ethyl ester

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

ethyl 2-((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)acetate

ethyl 2-((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)acetate

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

ethyl 2-((4aS,5S,8aR)-5,8a-dimethyl-6-methyleneoctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)acetate

ethyl 2-((4aS,5S,8aR)-5,8a-dimethyl-6-methyleneoctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)acetate

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

(4aS,5R,6S,8aR)-5-(2-Hydroxy-6-methoxy-benzyl)-5,6,8a-trimethyl-octahydro-naphthalen-1-one

(4aS,5R,6S,8aR)-5-(2-Hydroxy-6-methoxy-benzyl)-5,6,8a-trimethyl-octahydro-naphthalen-1-one

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

2-methoxy-3-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione

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上游原料

(2-methoxy-6-(methoxymethoxy)phenyl)((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methanol (4aS,8aR)-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbonitrile ethyl 2-((4aS,5S,8aR)-5,8a-dimethyl-6-methyleneoctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)acetate cis-decaline O-((2-methoxy-6-(methoxymethoxy)phenyl)((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl) S-methyl carbonodithioate (4aS,8aR)-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]-6-carbaldehyde ethyl 2-((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)acetate 5,8a-dimethyl-3,4,8,8a-tetrahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-6(7H)-one (4aS,8aR)-6-Hydroxymethyl-5,8a-dimethyl-3,4,4a,7,8,8a-hexahydro-2H-naphthalen-1-one (4aS,5R,6S,8aR)-5,6,8a-trimethyl-5-vinyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane] ((1S,4aR,8aS)-1,4a-Dimethyl-2-methylene-5-oxo-decahydro-naphthalen-1-yl)-acetic acid ethyl ester 3-methoxy-2-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)phenol (4aS,5R,6S,8aR)-5-(2-Hydroxy-6-methoxy-benzyl)-5,6,8a-trimethyl-octahydro-naphthalen-1-one (4aS,5R,6S,8aR)-5-(2-methoxy-6-(methoxymethoxy)benzyl)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolane]

下游产品

2,3-dichloro-5-methoxy-6-(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)cyclohexa-2,5-diene-1,4-dione 6-chloro-2'-hydroxy-4,4',5'-trimethoxy-3,3'-bis(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)-[1,1'-biphenyl]-2,5-dione 3,7,8-trimethoxy-2,6-bis(((4aS,5R,6S,8aR)-5,6,8a-trimethyloctahydro-2H-spiro[naphthalene-1,2'-[1,3]dioxolan]-5-yl)methyl)dibenzo[b,d]furan-1,4-dione popolohuanone E trimethyl ether 3,7,8-Trimethoxy-2,6-bis-((1R,2S,4aR,8aS)-1,2,4a-trimethyl-5-oxo-decahydro-naphthalen-1-ylmethyl)-dibenzofuran-1,4-dione