百科

(2R,3R,4R,5R,8S,10R)-3-tert-butyldimethylsilyloxy-2,4-dimethyl-5,8-epoxy-10-[N-methyl-N-(toluene-4-sulfonyl)amino]tridecan-1-ol

(2R,3R,4R,5R,8S,10R)-3-tert-butyldimethylsilyloxy-2,4-dimethyl-5,8-epoxy-10-[N-methyl-N-(toluene-4-sulfonyl)amino]tridecan-1-ol

CAS号：364597-87-5

英文名：(2R,3R,4R,5R,8S,10R)-3-tert-butyldimethylsilyloxy-2,4-dimethyl-5,8-epoxy-10-[N-methyl-N-(toluene-4-sulfonyl)amino]tridecan-1-ol

分子式：C29H53NO5SSi

分子量：555.885

合成路线

tert-butyl (R)-3-(toluene-4-sulfonylamino)hexanoate

tert-butyl (R)-3-(toluene-4-sulfonylamino)hexanoate

(2R,3R,4R,5R,8S,10R)-3-tert-butyldimethylsilyloxy-2,4-dimethyl-5,8-epoxy-10-[N-methyl-N-(toluene-4-sulfonyl)amino]tridecan-1-ol

(2R,3R,4R,5R,8S,10R)-3-tert-butyldimethylsilyloxy-2,4-dimethyl-5,8-epoxy-10-[N-methyl-N-(toluene-4-sulfonyl)amino]tridecan-1-ol

(2S,3R,6S,8R)-1-benzyloxy-8-[N-methyl-N-(toluene-4-sulfonyl)amino]-3,6-epoxy-2-methylundecane

(2S,3R,6S,8R)-1-benzyloxy-8-[N-methyl-N-(toluene-4-sulfonyl)amino]-3,6-epoxy-2-methylundecane

(2R,3R,4R,5R,8S,10R)-3-tert-butyldimethylsilyloxy-2,4-dimethyl-5,8-epoxy-10-[N-methyl-N-(toluene-4-sulfonyl)amino]tridecan-1-ol

(2R,3R,4R,5R,8S,10R)-3-tert-butyldimethylsilyloxy-2,4-dimethyl-5,8-epoxy-10-[N-methyl-N-(toluene-4-sulfonyl)amino]tridecan-1-ol

tert-butyl hex-2-enoate

tert-butyl hex-2-enoate

(2R,3R,4R,5R,8S,10R)-3-tert-butyldimethylsilyloxy-2,4-dimethyl-5,8-epoxy-10-[N-methyl-N-(toluene-4-sulfonyl)amino]tridecan-1-ol

(2R,3R,4R,5R,8S,10R)-3-tert-butyldimethylsilyloxy-2,4-dimethyl-5,8-epoxy-10-[N-methyl-N-(toluene-4-sulfonyl)amino]tridecan-1-ol

上游原料

tert-butyl hex-2-enoate (2S,3R,6S,8R)-1-benzyloxy-8-[N-methyl-N-(toluene-4-sulfonyl)amino]-3,6-epoxy-2-methylundecane tert-butyl (R)-3-(toluene-4-sulfonylamino)hexanoate

下游产品

(2R,6S,7R,8R,9R,10R,13S,15R,3Z)-1-benzyloxy-8-tert-butyldimethylsilyloxy-10,13-epoxy-15-[N-methyl-N-(toluene-4-sulfonyl)amino]-2,7,9-trimethyloctadec-3-en-6-ol (2S,3R,6S,8R)-1-benzyloxy-8-[N-methyl-N-(toluene-4-sulfonyl)amino]-3,6-epoxy-2-methylundecane