百科

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

CAS号：370066-70-9

英文名：[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

分子式：C27H58O4Si3

分子量：531.004

合成路线

(3R,4R,5R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-triethylsilanyloxy-heptane-1,2-diol

(3R,4R,5R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-triethylsilanyloxy-heptane-1,2-diol

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

(3R,4R,5S,6R)-3,5-Dimethyl-6-triethylsilanyloxy-hept-1-en-4-ol

(3R,4R,5S,6R)-3,5-Dimethyl-6-triethylsilanyloxy-hept-1-en-4-ol

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

(2R,3R)-ethyl 2-methyl-3-((triethylsilyl)oxy)butanoate

(2R,3R)-ethyl 2-methyl-3-((triethylsilyl)oxy)butanoate

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

3-hydroxy-2-methylbutanoic acid

3-hydroxy-2-methylbutanoic acid

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-4-hydroxy-5,7-dimethyl-3-methoxy-8-[(triethylsilyl)oxy]-1-trimethylsilylnon-1-yne

上游原料

(2R,3R)-ethyl 2-methyl-3-((triethylsilyl)oxy)butanoate (3R,4R,5S,6R)-3,5-Dimethyl-6-triethylsilanyloxy-hept-1-en-4-ol (3R,4R,5R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-triethylsilanyloxy-heptane-1,2-diol

下游产品

Benzoic acid (1R,2R,3R,4S,7R,8S,9R)-3-(tert-butyl-dimethyl-silanyloxy)-9-(diethyl-isopropyl-silanyloxy)-7-hydroxy-1-((S)-1-methoxy-3-trimethylsilanyl-prop-2-ynyl)-2,4,8-trimethyl-5-oxo-decyl ester (3S,4R,5R,6R,7S)-3,5-dimethyl-4-[(tert-butyldimethyl)siloxy]-6-[(benzoyl)oxy]-7-methoxynon-8-yn-2-one