百科

(3S,6R,7S,8S)-11-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-1,3,7-tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-undecan-5-one

(3S,6R,7S,8S)-11-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-1,3,7-tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-undecan-5-one

CAS号：371785-06-7

英文名：(3S,6R,7S,8S)-11-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-1,3,7-tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-undecan-5-one

分子式：C44H84O5Si3

分子量：777.391

合成路线

(S)-5-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-2-methyl-pentan-1-ol

(S)-5-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-2-methyl-pentan-1-ol

(3S,6R,7S,8S)-11-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-1,3,7-tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-undecan-5-one

(3S,6R,7S,8S)-11-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-1,3,7-tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-undecan-5-one

(E)-(S)-8-(tert-Butyl-diphenyl-silanyloxy)-7-methyl-oct-2-en-1-ol

(E)-(S)-8-(tert-Butyl-diphenyl-silanyloxy)-7-methyl-oct-2-en-1-ol

(3S,6R,7S,8S)-11-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-1,3,7-tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-undecan-5-one

(3S,6R,7S,8S)-11-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-1,3,7-tris-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-undecan-5-one

上游原料

(E)-(S)-8-(tert-Butyl-diphenyl-silanyloxy)-7-methyl-oct-2-en-1-ol (S)-5-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-2-methyl-pentan-1-ol

下游产品

(3S,6R,7S,8S)-3,7-Bis-(tert-butyl-dimethyl-silanyloxy)-11-((1R,2R)-2-hydroxymethyl-cyclopropyl)-4,4,6,8-tetramethyl-5-oxo-undecanoic acid methyl ester (3S,6R,7S,8S)-11-((1R,2R)-2-Benzyloxymethyl-cyclopropyl)-3,7-bis-(tert-butyl-dimethyl-silanyloxy)-4,4,6,8-tetramethyl-5-oxo-undecanoic acid methyl ester