(S)-2-[(2S,5R,2'R,5'R,2''S,5''R)-5''-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl]-6-methyl-hept-5-en-2-ol

(S)-2-[(2S,5R,2'R,5'R,2''S,5''R)-5''-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl]-6-methyl-hept-5-en-2-ol

CAS号：372075-35-9

英文名：(S)-2-[(2S,5R,2'R,5'R,2''S,5''R)-5''-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl]-6-methyl-hept-5-en-2-ol

分子式：C30H52O5

分子量：492.731

合成路线

(E)-(S)-2-{(2R,5R)-5-[(E)-(S)-1-Hydroxy-1,5-dimethyl-7-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-tetrahydro-furan-2-yl}-6-methyl-8-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-oct-5-en-2-ol

(E)-(S)-2-{(2R,5R)-5-[(E)-(S)-1-Hydroxy-1,5-dimethyl-7-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-tetrahydro-furan-2-yl}-6-methyl-8-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-oct-5-en-2-ol

(S)-2-[(2S,5R,2'R,5'R,2''S,5''R)-5''-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl]-6-methyl-hept-5-en-2-ol

(S)-2-[(2S,5R,2'R,5'R,2''S,5''R)-5''-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl]-6-methyl-hept-5-en-2-ol

(S)-2-{(2S,5R,2'R,5'R,2''S,5''R)-5''-[(S)-1-Hydroxy-1-methyl-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-propyl]-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl}-4-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-butan-2-ol

(S)-2-{(2S,5R,2'R,5'R,2''S,5''R)-5''-[(S)-1-Hydroxy-1-methyl-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-propyl]-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl}-4-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-butan-2-ol

(S)-2-[(2S,5R,2'R,5'R,2''S,5''R)-5''-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl]-6-methyl-hept-5-en-2-ol

(S)-2-[(2S,5R,2'R,5'R,2''S,5''R)-5''-((S)-1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl]-6-methyl-hept-5-en-2-ol

上游原料

(S)-2-{(2S,5R,2'R,5'R,2''S,5''R)-5''-[(S)-1-Hydroxy-1-methyl-3-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-propyl]-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl}-4-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-butan-2-ol (E)-(S)-2-{(2R,5R)-5-[(E)-(S)-1-Hydroxy-1,5-dimethyl-7-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-hept-4-enyl]-tetrahydro-furan-2-yl}-6-methyl-8-((S)-2,2,5,5-tetramethyl-[1,3]dioxolan-4-yl)-oct-5-en-2-ol

下游产品

(E)-(S)-6-Hydroperoxy-2-[(2S,5R,2'R,5'R,2''S,5''R)-5''-((E)-(S)-5-hydroperoxy-1-hydroxy-1,5-dimethyl-hex-3-enyl)-2,2''-dimethyl-dodecahydro-[2,2';5',2'']terfuran-5-yl]-6-methyl-hept-4-en-2-ol