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[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
CAS号:381247-20-7
英文名:[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
分子式:C34H70O5S2Si2
分子量:679.218
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合成路线
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(-)-(2S,3R,4R)-2,4-bis(tert-butyldimethylsiloxy)-1-iodo-3,5-dimethylhexane
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[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
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(2R,3R,4R,5S,6S)-6-Benzyloxymethoxy-2,7-dihydroxy-4-methoxymethoxy-3,5-dimethyl-heptanoic acid methyl ester
381247-20-7
[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
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(R)-2-Benzyloxymethoxy-3-methyl-butyraldehyde
381247-20-7
[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
381247-05-8
(R)-2-Benzyloxymethoxy-3-methyl-butyric acid methyl ester
381247-20-7
[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
381247-06-9
(R)-2-Benzyloxymethoxy-3-methyl-butan-1-ol
381247-20-7
[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
381246-76-0
(3S,4R)-4-benzyloxymethoxy-3,5-dimethylhexanoic acid methyl ester
381247-20-7
[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
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(2S,3S,4R)-4-benzyloxymethoxy-2-hydroxy-3,5-dimethylhexanoic acid methyl ester
381247-20-7
[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
381247-08-1
(2S,3R,4R)-4-Benzyloxymethoxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexan-1-ol
381247-20-7
[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
381247-07-0
(2S,3R,4R)-4-Benzyloxymethoxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexanoic acid methyl ester
381247-20-7
[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
381246-77-1
2,2-dimethylpropionic acid (2S,3R,4R)-4-benzyloxymethoxy-2-(tert-butyldimethylsilanyloxy)-3,5-dimethylhexyl ester
381247-20-7
[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol
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上游原料
(2R,3S,4R,5S)-1-(tert-Butyl-diphenyl-silanyloxy)-5-[1,3]dithian-2-yl-3-methyl-hexane-2,4-diol
(2S,3R,4R)-4-Benzyloxymethoxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexanoic acid methyl ester
(2R,3S,4R,5S)-5-[1,3]Dithian-2-yl-3-methyl-hexane-1,2,4-triol
(+)-(2S,3R,4R)-2,4-bis(tert-butyldimethylsiloxy)-3,5-dimethylhexan-1-ol
(2S,3S,4R)-4-benzyloxymethoxy-2-hydroxy-3,5-dimethylhexanoic acid methyl ester
(2S,3R,4R)-4-Benzyloxymethoxy-2-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexan-1-ol
(R)-2-Benzyloxymethoxy-3-methyl-butan-1-ol
(3S,4R)-4-benzyloxymethoxy-3,5-dimethylhexanoic acid methyl ester
(R)-2-Benzyloxymethoxy-3-methyl-butyraldehyde
(R)-2-Benzyloxymethoxy-3-methyl-butyric acid methyl ester
tert-butyl-[(4R,5S,6R)-6-((S)-1-[1,3]dithian-2-yl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl-methoxy]-diphenylsilane
(2R,3R,4R,5S,6S)-6-[(benzyloxy)methoxy]-7-(tert-butyldiphenylsilanyloxy)-2-hydroxy-4-methoxymethoxy-3,5-dimethylheptanoic acid methyl ester
(2R,3R,4R,5S,6S)-6-Benzyloxymethoxy-2,7-dihydroxy-4-methoxymethoxy-3,5-dimethyl-heptanoic acid methyl ester
(3R,4R,5R)-5-((S)-1-[1,3]dithian-2-yl-ethyl)-3-hydroxy-4-methyldihydro-furan-2-one
2,2-dimethylpropionic acid (2S,3R,4R)-4-benzyloxymethoxy-2-(tert-butyldimethylsilanyloxy)-3,5-dimethylhexyl ester
(4R,5S,6R)-4-((S)-1-{2-[(2R,3S,4R)-2,4-bis(tert-butyldimethylsilanyloxy)-3,5-dimethylhexyl]-[1,3]dithian-2-yl}-ethyl)-6-(tert-butyldiphenylsilanyloxymethyl)-2,2,5-trimethyl-[1,3]dioxane
(-)-(2S,3R,4R)-2,4-bis(tert-butyldimethylsiloxy)-1-iodo-3,5-dimethylhexane
(2R,3R,4S,5R,6S)-2,6,7-Trihydroxy-4-methoxymethoxy-3,5-dimethyl-heptanoic acid methyl ester
下游产品
(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-bis(tert-butyldimethylsilanyloxy)-3,5-dimethylhexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxane-4-carbaldehyde
1-[(4R,5S,6R)-6-((S)-1-{2-[(2R,3S,4R)-2,4-Bis-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-hexyl]-[1,3]dithian-2-yl}-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-propynone