百科

(R)-6-[(E)-(3R,4R)-4-(4-Methoxy-benzyloxy)-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

(R)-6-[(E)-(3R,4R)-4-(4-Methoxy-benzyloxy)-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

CAS号：381665-42-5

英文名：(R)-6-[(E)-(3R,4R)-4-(4-Methoxy-benzyloxy)-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

分子式：C31H46O6Si2

分子量：570.864

合成路线

(E)-(2R,3R)-5-((2R,6R)-6-Isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3-methyl-3-triethylsilanyloxy-1-(2-trimethylsilanylethynyl-[1,3]dithian-2-yl)-pent-4-en-2-ol

(E)-(2R,3R)-5-((2R,6R)-6-Isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3-methyl-3-triethylsilanyloxy-1-(2-trimethylsilanylethynyl-[1,3]dithian-2-yl)-pent-4-en-2-ol

(R)-6-[(E)-(3R,4R)-4-(4-Methoxy-benzyloxy)-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

(R)-6-[(E)-(3R,4R)-4-(4-Methoxy-benzyloxy)-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

2-<(trimethylsilyl)ethynyl>-1,3-dithiane

2-<(trimethylsilyl)ethynyl>-1,3-dithiane

(R)-6-[(E)-(3R,4R)-4-(4-Methoxy-benzyloxy)-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

(R)-6-[(E)-(3R,4R)-4-(4-Methoxy-benzyloxy)-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

上游原料

2-<(trimethylsilyl)ethynyl>-1,3-dithiane (E)-(2R,3R)-5-((2R,6R)-6-Isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3-methyl-3-triethylsilanyloxy-1-(2-trimethylsilanylethynyl-[1,3]dithian-2-yl)-pent-4-en-2-ol

下游产品

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-8-iodo-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one (R)-6-[(E)-(3R,4R,6R)-6-Hydroxy-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one (R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one