百科

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

CAS号：381665-52-7

英文名：(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

分子式：C37H62O6Si3

分子量：687.141

合成路线

381665-50-5

(E)-(2R,3R)-5-((2R,6R)-6-Isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3-methyl-3-triethylsilanyloxy-1-(2-trimethylsilanylethynyl-[1,3]dithian-2-yl)-pent-4-en-2-ol

381665-52-7

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

76649-03-1

2-<(trimethylsilyl)ethynyl>-1,3-dithiane

381665-52-7

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

381665-48-1

(2R,6R)-2-ethynyl-6-isopropoxy-3,6-dihydro-2H-pyran

381665-52-7

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

381665-49-2

Triethyl-[(E)-(R)-3-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-1-methyl-1-(R)-oxiranyl-allyloxy]-silane

381665-52-7

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

381665-51-6

(R)-6-((E)-(3R,4R)-4-Hydroxy-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl)-5,6-dihydro-pyran-2-one

381665-52-7

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

381665-41-4

(R)-6-[(E)-(3R,4R)-4-Hydroxy-3-methyl-3-triethylsilanyloxy-5-(2-trimethylsilanylethynyl-[1,3]dithian-2-yl)-pent-1-enyl]-5,6-dihydro-pyran-2-one

381665-52-7

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

381665-42-5

(R)-6-[(E)-(3R,4R)-4-(4-Methoxy-benzyloxy)-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

381665-52-7

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one

上游原料

(2R,6R)-2-ethynyl-6-isopropoxy-3,6-dihydro-2H-pyran Triethyl-[(E)-(R)-3-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-1-methyl-1-(R)-oxiranyl-allyloxy]-silane (R)-6-((E)-(3R,4R)-4-Hydroxy-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl)-5,6-dihydro-pyran-2-one (R)-6-[(E)-(3R,4R)-4-Hydroxy-3-methyl-3-triethylsilanyloxy-5-(2-trimethylsilanylethynyl-[1,3]dithian-2-yl)-pent-1-enyl]-5,6-dihydro-pyran-2-one (R)-6-[(E)-(3R,4R)-4-(4-Methoxy-benzyloxy)-3-methyl-6-oxo-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one 2-<(trimethylsilyl)ethynyl>-1,3-dithiane (E)-(2R,3R)-5-((2R,6R)-6-Isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3-methyl-3-triethylsilanyloxy-1-(2-trimethylsilanylethynyl-[1,3]dithian-2-yl)-pent-4-en-2-ol

下游产品

(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-8-iodo-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one (6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one (R)-6-((3R,4R,6R,E)-6-(tert-butyldimethylsilyloxy)-4-hydroxy-8-iodo-3-methyl-3-(triethylsilyloxy)oct-1-en-7-ynyl)-5,6-dihydro-2H-pyran-2-one